2,6-Diphospha-s-indacene-1,3,5,7(2H,6H)-tetraone: A Phosphorus Analogue of Aromatic Diimides with the Minimal Core Exhibiting High Electron-Accepting Ability

Youhei Takeda; Takuya Nishida; Satoshi Minakata

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2,6-Diphospha-s-indacene-1,3,5,7(2H,6H)-tetraone: A Phosphorus Analogue of Aromatic Diimides with the Minimal Core Exhibiting High Electron-Accepting Ability

机译：2,6-Diphospha-s-indacene-1,3,5,7（2H，6H）-tetraone：磷二芳族芳香族亚胺的磷类似物，具有高电子接受能力

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Phosphorus analogues of pyrromellitic diimides (PyDIs), which represent a family of privileged electron-accepting organic compounds, have been successfully synthesized as novel electron-accepting p-conjugated molecules. Investigation into their physicochemical properties uncovered their prominent electron-accepting abilities over the corresponding PyDI. Furthermore, theoretical studies revealed the significant contribution of σ*–π* hyperconjugation in stabilizing the LUMO+1.

机译：均苯四甲酸二酰亚胺（PyDIs）的磷类似物代表了一系列优先的电子接受有机化合物，已成功合成为新型电子接受p共轭分子。对它们的理化性质的研究发现它们在相应的PyDI上具有显着的电子接受能力。此外，理论研究还揭示了σ* –π *超共轭在稳定LUMO + 1中的重要作用。

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《Chemistry: A European journal》 |2014年第33期|共5页
作者
Youhei Takeda; Takuya Nishida; Satoshi Minakata;
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Phosphorus; analogues; pyrromellitic;

机译：磷;类似物;均苯四甲酸;

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1. 2,6-Diphospha-s-indacene-1,3,5,7(2H,6H)-tetraone: A Phosphorus Analogue of Aromatic Diimides with the Minimal Core Exhibiting High Electron-Accepting Ability [J] . Youhei Takeda, Takuya Nishida, Satoshi Minakata Chemistry: A European journal . 2014,第33期

机译：2,6-Diphospha-s-indacene-1,3,5,7（2H，6H）-tetraone：磷二芳族芳香族亚胺的磷类似物，具有高电子接受能力
2. Crystal structure of 2,6-bis(3-methylpyridinyl) hexahydro-4,8-ethenopyrrolo-[3,4-f]isoindole-1,3,5,7(2H, 6H)-tetrone, C24H20N4O4 [J] . Liu Zhi-Min Zeitschrift fur Kristallographie. New crystal structures . 2016,第2期

机译：2,6-双（3-甲基吡啶基）六氢-4,8-乙炔吡咯-[3,4-f]异吲哚-1,3,5,7（2H，6H）-四烯的晶体结构，C24H20N4O4
3. 2,6-Bis[(S)-1-phenylethyl]-1H,5H-pyrrolo[3,4-f]isoindole-1,3,5,7(2H,6H)-tetrone [J] . Abdel-Aziz A.A.-M., Alanazi A.M., El-Azab A.S., Acta Crystallographica Section E: Crystallographic Communications . 2012,第3期

机译：2,6-双[（S）-1-苯乙基] -1H，5H-吡咯并[3,4-f]异吲哚-1,3,5,7（2H，6H）-四元
4. Investigation of Third Order Nonlinear Optical Properties in s-Indacene-1,3,5,7(2H,6H)-tetraone Based D-π-A-π-D Chromophores by Z-scan [C] . R. D. Breukers, A. P. Middleton, S. Janssens, Optical processes in organic materials and nanostructures II . 2013

机译：Z-扫描研究基于s-茚并-1,3,5,7（2H，6H）-四酮的D-π-A-π-D发色团的三阶非线性光学性质
5. Crystal structure of 2,6-bis(2-(pyridin-3-yl)ethyl)pyrrolo3,4-fisoindole-1,3,5,7(2H,6H)-tetraone, C24H18N4O4 [O] . Yu Jeong Jeong, Juhyeon Park, Ahreum Min, 2021

机译：2,6-双（2-（吡啶-3-基）乙基）吡咯的晶体结构3,4-F异吲哚-1,3,5,7（2h，6h） - 44h18n4O4

2,6-Diphospha-s-indacene-1,3,5,7(2H,6H)-tetraone: A Phosphorus Analogue of Aromatic Diimides with the Minimal Core Exhibiting High Electron-Accepting Ability

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