Structural Effects in Lithiocuprate Chemistry: The Elucidation of Reactive Pentametallic Complexes

Philip J. Harford; Andrew J. Peel; Joseph P. Taylor; Shinsuke Komagawa; Paul R. Raithby; Thomas P. Robinson; Masanobu Uchiyama; Andrew E. H. Wheatley

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Structural Effects in Lithiocuprate Chemistry: The Elucidation of Reactive Pentametallic Complexes

机译：硫代铜酸盐化学中的结构效应：活性五金属配合物的阐明

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TMPLi (TMP=2,2,6,6-tetramethylpiperidide) reacts with Cu~I salts in the presence of Et_2O to give the dimers [{(TMP)_2Cu(X)Li_2(OEt_2)}_2] (X=CN, halide). In contrast, the use of DMPLi (DMP=cis-2,6-dimethylpiperidide) gives an unprecedented structural motif; [{(DMP)_2CuLi- (OEt_2)}_2LiX] (X=halide). This formulation suggests a hitherto unexplored route to the in situ formation of Gilmantype bases that are of proven reactivity in directed ortho cupration.

机译：TMPLi（TMP = 2,2,6,6-四甲基哌啶）在Et_2O存在下与Cu〜I盐反应生成二聚体[{（TMP）_2Cu（X）Li_2（OEt_2）} _ 2]（X = CN，卤化物）。相比之下，使用DMPLi（DMP = cis-2,6-二甲基哌啶）可获得前所未有的结构基序。 [{（DMP）_2CuLi-（OEt_2）} _ 2LiX]（X =卤化物）。该配方表明迄今尚未发现的吉尔曼型碱基原位形成途径，已证明在定向邻位拔罐中具有反应活性。

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《Chemistry: A European journal》 |2014年第14期|共5页
作者
Philip J. Harford; Andrew J. Peel; Joseph P. Taylor; Shinsuke Komagawa; Paul R. Raithby; Thomas P. Robinson; Masanobu Uchiyama; Andrew E. H. Wheatley;
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正文语种 eng
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copper; density functional calculations; directed metalation; lithium; solid-state structures;

机译：铜;密度泛函计算;定向金属化;锂;固态结构;

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1. Structural Effects in Lithiocuprate Chemistry: The Elucidation of Reactive Pentametallic Complexes [J] . Philip J. Harford, Andrew J. Peel, Joseph P. Taylor, Chemistry: A European journal . 2014,第14期

机译：硫代铜酸盐化学中的结构效应：活性五金属配合物的阐明
2. Extending motifs in lithiocuprate chemistry: unexpected structural diversity in thiocyanate complexes [J] . Peel Andrew J., Hedidi Madani, Bentabed-Ababsa Ghenia, Dalton transactions: An international journal of inorganic chemistry . 2016,第14期

机译：扩展硫代铜酸盐化学中的基序：硫氰酸盐络合物中意外的结构多样性
3. Certain New Organic-Inorganic Hybrid Complexes of Monobutyltin(Iv) of β-Diketones / Fluorinated β-Diketone and Sterically Congested Heterocyclic β-Diketones : Preparation, Structural Chemistry and Structural Elucidation Based upon Spectroscopic [Ir and Nmr (~1H, ~(13)C and ~(119)Sn)] Studies [J] . Ritu Kumari Gupta, Asha Jain and Sanjiv Saxena Main Group Metal Chemistry . 2010,第4a5期

机译：β-二酮/氟化β-二酮和立体拥挤的杂环β-二酮的单丁基锡（Iv）的某些新型有机-无机杂化配合物：基于光谱[Ir和Nmr（〜1H，〜（13）的制备，结构化学和结构解析）C和〜（119）Sn）]研究
4. Synthesis,structural elucidation and antimicrobial activities of 5-(3-nitrophenyllazo)-6-aminouracil and its complexes with some transition metal ions [C] . Z M Zaki, S M Abbas, H A Dessoukii International Conference on Advanced Sciences . 2018

机译：5-（3-硝基苯齐噻唑）-6-Aminouracil的合成，结构阐明和抗微生物活性及其络合物与一些过渡金属离子
5. The role of solvation on ion -molecule reactions: Elucidating mechanisms of heterogeneous atmospheric chemistry and the reactivity of metal -ligand complexes. [D] . Gilligan, John Joseph. 2000

机译：溶剂化在离子分子反应中的作用：阐明异质大气化学机制和金属-配体络合物的反应性。
6. Structural Effects in Lithiocuprate Chemistry: The Elucidation of Reactive Pentametallic Complexes [O] . Philip J Harford, Andrew J Peel, Joseph P Taylor, -1

机译：硫代铜酸盐化学中的结构效应：活性五金属配合物的阐明
7. Structural effects in lithiocuprate chemistry:the elucidation of reactive pentametallic complexes [O] . Harford Philip J., Peel Andrew J., Taylor Joseph P., 2014

机译：硫代铜酸盐化学中的结构效应：反应性五金属配合物的阐明

Structural Effects in Lithiocuprate Chemistry: The Elucidation of Reactive Pentametallic Complexes

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