Corannulene Molecular Rotor with Flexible Perfluorobenzyl Blades: Synthesis, Structure and Properties

San Long K.; Clikeman Tyler T.; Dubceac Cristina; Popov Alexey A.; Chen Yu-Sheng; Petrukhina Marina A.; Strauss Steven H.; Boltalina Olga V.

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Corannulene Molecular Rotor with Flexible Perfluorobenzyl Blades: Synthesis, Structure and Properties

机译：具有柔性全氟苄基叶片的Corannulene分子转子：合成，结构和性能

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Two members of a new class of organic-acceptor perfluorobenzyl corannulenes were prepared by gas-phase and highly-selective solution-phase reactions at elevated temperatures. The peculiar single-crystal X-ray structure of C-5-C20H5(CF2C6F5)(5) revealed two high-energy conformers with drastically different bowl depths and orientations of perfluorobenzyl blades; the conformers are alternating in columnar packing arrangements and every pair is sandwiched by toluene molecules.

机译：通过在高温下进行气相和高选择性溶液相反应，制备了新型一类有机受体全氟苄基环戊二烯。 C-5-C20H5（CF2C6F5）（5）特有的单晶X射线结构显示了两个高能构象体，其碗深和全氟苄基叶片的取向截然不同;构象体以柱状堆积排列交替排列，每对被甲苯分子夹在中间。

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来源
《Chemistry: A European journal》 |2015年第26期|共5页
作者
San Long K.; Clikeman Tyler T.; Dubceac Cristina; Popov Alexey A.; Chen Yu-Sheng; Petrukhina Marina A.; Strauss Steven H.; Boltalina Olga V.;
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正文语种 eng
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关键词
corannulenes; electron acceptors; electron withdrawing; flexible conformer; structure elucidation;

机译：Corannulenes;电子受体;吸电子;柔性构象体;结构阐明;

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专利

1. Corannulene Molecular Rotor with Flexible Perfluorobenzyl Blades: Synthesis, Structure and Properties [J] . San Long K., Clikeman Tyler T., Dubceac Cristina, Chemistry: A European journal . 2015,第26期

机译：具有柔性全氟苄基叶片的Corannulene分子转子：合成，结构和性能
2. Gas phase synthesis and X-ray crystal structures of supramolecular networks with bromocorannulene: Similarities and differences with their corannulene analogs [J] . Filatov AS, Petrukhina MA Journal of Organometallic Chemistry . 2008,第8a9期

机译：含溴环戊二烯的超分子网络的气相合成和X射线晶体结构：与Corannulene类似物的异同
3. Synthesis, Properties, and Packing Structures of Corannulene-Based -Systems Containing Heptagons [J] . Kato Kenta, Segawa Yasutomo, Scott Lawrence T., Chemistry, an Asian journal . 2015,第8期

机译：含有七边形的基于Corannulene的系统的合成，性质和堆积结构
4. Structured modeling applied to flexible thelicopter rotor blades [C] . Amnon Katz, Kyle Palmer AHS international annual forum . 2000

机译：结构化建模应用于柔性直升机旋翼桨叶
5. The Design, Synthesis, and Study of Solid-State Molecular Rotors: Structure/Function Relationships for Condensed-Phase Anisotropic Dynamics. [D] . Vogelsberg, Cortnie Sue. 2012

机译：固态分子转子的设计，合成和研究：凝聚相各向异性动力学的结构/功能关系。
6. Synthesis and Properties of Bis-Porphyrin Molecular Tweezers: Effects of Spacer Flexibility on Binding and Supramolecular Chirogenesis [O] . Magnus Blom, Sara Norrehed, Claes-Henrik Andersson, 2016

机译：双卟啉分子镊子的合成和性质：间隔物柔性对结合和超分子手性的影响。
7. Theory of Rotor Dynamics With Coupling of Disk and Blade Flexibility and Support Structure Asymmetry [O] . Nicholas Klompas 1974

机译：转子动力学理论，圆盘耦合和叶片柔性和支撑结构不对称

Corannulene Molecular Rotor with Flexible Perfluorobenzyl Blades: Synthesis, Structure and Properties

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