Ionic Conductivity of beta-Cyclodextrin-Polyethylene-Oxide/Alkali-Metal-Salt Complex

Yang Ling-Yun; Fu Xiao-Bin; Chen Tai-Qiang; Pan Li-Kun; Ji Peng; Yao Ye-Feng; Chen Qun

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Ionic Conductivity of beta-Cyclodextrin-Polyethylene-Oxide/Alkali-Metal-Salt Complex

机译：β-环糊精-聚乙烯-氧化物/碱-金属盐复合物的离子电导率

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Highly conductive, crystalline, polymer electrolytes, -cyclodextrin (-CD)-polyethylene oxide (PEO)/LiAsF6 and -CD-PEO/NaAsF6, were prepared through supramolecular self-assembly of PEO, -CD, and LiAsF6/NaAsF6. The assembled -CDs form nanochannels in which the PEO/X+ (X=Li, Na) complexes are confined. The nanochannels provide a pathway for directional motion of the alkali metal ions and, at the same time, separate the cations and the anions by size exclusion.

机译：通过PEO，-CD和LiAsF6 / NaAsF6的超分子自组装制备了高导电性的结晶聚合物电解质-环糊精（-CD）-聚环氧乙烷（PEO）/ LiAsF6和-CD-PEO / NaAsF6。组装的-CD形成纳米通道，其中PEO / X +（X = Li，Na）络合物被限制在其中。纳米通道为碱金属离子的定向运动提供了途径，同时通过尺寸排阻将阳离子和阴离子分开。

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来源
《Chemistry: A European journal》 |2015年第17期|共4页
作者
Yang Ling-Yun; Fu Xiao-Bin; Chen Tai-Qiang; Pan Li-Kun; Ji Peng; Yao Ye-Feng; Chen Qun;
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正文语种 eng
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inclusion complexes; ion transport; molecular dynamics; polymer electrolytes; solid-state NMR;

机译：包合物;离子迁移;分子动力学;聚合物电解质;固态NMR;

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1. Ionic Conductivity of beta-Cyclodextrin-Polyethylene-Oxide/Alkali-Metal-Salt Complex [J] . Yang Ling-Yun, Fu Xiao-Bin, Chen Tai-Qiang, Chemistry: A European journal . 2015,第17期

机译：β-环糊精-聚乙烯-氧化物/碱-金属盐复合物的离子电导率
2. Effect of EMIMBF4 ionic liquid addition on the structure and ionic conductivity of LiBF4-complexed PVdF-HFP polymer electrolyte films [J] . Tang Jiwu, Muchakayala Ravi, Song Shenhua, Polymer Testing . 2016,第Null期

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Ionic Conductivity of beta-Cyclodextrin-Polyethylene-Oxide/Alkali-Metal-Salt Complex

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