Designing Artificial 3D Helicates: Unprecedented Self-Assembly of Homo-octanuclear Tetrapods with Europium

Zebret Soumaila; Voegele Eliane; Klumpler Tomas; Hamacek Josef

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Designing Artificial 3D Helicates: Unprecedented Self-Assembly of Homo-octanuclear Tetrapods with Europium

机译：设计人工3D螺旋桨：同oc四足体与with的前所未有的自组装

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Herein, we report on the rational design, preparation and characterization of a novel homo-octanuclear helicate, which results from a spatial extension of the central tetranuclear platform. The 3D supramolecular assembly is obtained by complexing europium(III) with a new hexatopic tripodal ligand. The isolated octanuclear helicate is fully characterized by different methods clearly evidencing the structure predicted with molecular modelling. The ligand preorganization plays a crucial role in a successful self-assembly process and induces the formation of a well-defined triple-stranded helical structure. This prototypal octanuclear edifice accommodating functional lanthanides within a 3D scaffold offers attractive perspectives for further applications.

机译：在这里，我们报告了一种合理的设计，制备和表征新型同八角螺旋，这是由于中央四核平台的空间扩展。通过将euro（III）与新的六位三脚架配体络合获得3D超分子组装体。分离出的八核螺旋体通过不同的方法得到充分表征，清楚地证明了分子建模预测的结构。配体的预组织在成功的自组装过程中起着至关重要的作用，并诱导形成定义明确的三链螺旋结构。在3D支架中容纳功能性镧系元素的原型八角大楼为进一步的应用提供了诱人的前景。

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《Chemistry: A European journal》 |2015年第18期|共5页
作者
Zebret Soumaila; Voegele Eliane; Klumpler Tomas; Hamacek Josef;
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正文语种 eng
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europium; helicates; octanuclear; self-assembly; supramolecular chemistry;

机译：hel;螺旋;核;自组装;超分子化学;

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1. Designing Artificial 3D Helicates: Unprecedented Self-Assembly of Homo-octanuclear Tetrapods with Europium [J] . Zebret Soumaila, Voegele Eliane, Klumpler Tomas, Chemistry: A European journal . 2015,第18期

机译：设计人工3D螺旋桨：同oc四足体与with的前所未有的自组装
2. Formation of Enantiomerically Pure Luminescent Triple-Stranded Dimetallic Europium Helicates and Their Corresponding Hierarchical Self-Assembly Formation in Protic Polar Solutions [J] . Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2020,第5期

机译：形成对纯纯发光三股二股二次铕螺旋及其在质子极性溶液中相应的等级自组装形成
3. Point Chirality Controlled Diastereoselective Self-Assembly and Circularly Polarized Luminescence in Quadruple-Stranded Europium(III) Helicates [J] . Zhou Yanyan, Yao Yuan, Cheng Zhenyu, Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2020,第17期

机译：点性儿童控制的非对抗选择自组装和四重绞合铕（III）螺旋中的圆偏振发光
4. Lanthanide helicates: from self-assembly to functionality [C] . Jean-Claude G. Biinzli Rare Earth Research Conference . 2019

机译：镧系螺旋螺旋：从自动组装到功能
5. Designing Parametric Matter: Exploring Adaptive Material Scale Self-Assembly Through Tuneable Environments [D] . Blaney, Adam. 2020

机译：设计参数物质：通过可调环境探索自适应材料尺度自组装
6. Supramolecular Chemistry And Self-assembly Special Feature: Configurationally homogeneous diastereomers of a linearhexa(tertiary phosphine): Enantioselective self-assembly of adouble-stranded parallel helicate of the type(P)-Cu3(hexaphos)2(PF6)3 [O] . Paul K. Bowyer, Vernon C. Cook, Nahid Gharib-Naseri, 2002

机译：超分子化学和自组装特征：线性的构型均一非对映异构体六（叔膦）：对映体的自组装类型的双链平行螺旋（P）-Cu3（hexaphos）2（PF6）3
7. Point Chirality Controlled Diastereoselective Self-Assembly and Circularly Polarized Luminescence in Quadruple-Stranded Europium(III) Helicates [O] . -1

机译：点性儿童控制的非对抗选择自组装和四重绞合铕（III）螺旋中的圆偏振发光

Designing Artificial 3D Helicates: Unprecedented Self-Assembly of Homo-octanuclear Tetrapods with Europium

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