Alkyl Halide-Free Heteroatom Alkylation and Epoxidation Facilitated by a Recyclable Polymer-Supported Oxidant for the In-Flow Preparation of Diazo Compounds

Nicolle Simon M.; Hayes Christopher J.; Moody Christopher J.

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Alkyl Halide-Free Heteroatom Alkylation and Epoxidation Facilitated by a Recyclable Polymer-Supported Oxidant for the In-Flow Preparation of Diazo Compounds

机译：可循环使用的聚合物支撑氧化剂在重氮化合物流式制备中的无卤卤杂原子烷基化和环氧化作用

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Highly reactive metal carbenes, generated from simple ketones via diazo compounds, including diazo-amides and -phosphonates, using a recyclable reagent in-flow, are transient but versatile electrophiles for heteroatom alkylation reactions and for epoxide formation. The method produces no organic waste, with the only by-products being water, KI and nitrogen, without the attendant hazards of isolation of intermediate diazo compounds.

机译：由简单的酮通过重氮化合物（包括重氮酰胺和-膦酸酯）经重氮化合物（包括重氮酰胺和正膦酸酯）生成的高反应性金属卡宾是短暂但通用的亲电子试剂，可用于杂原子烷基化反应和环氧化物的形成。该方法不产生有机废物，唯一的副产物是水，KI和氮气，并且没有分离中间体重氮化合物的伴随危险。

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《Chemistry: A European journal》 |2015年第12期|共4页
作者
Nicolle Simon M.; Hayes Christopher J.; Moody Christopher J.;
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正文语种 eng
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关键词
alkylation; carbenes; epoxidation; oxidation; recyclable supported reagents;

机译：烷基化;卡宾;环氧化;氧化;可循环利用的支持试剂;

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1. Alkyl Halide-Free Heteroatom Alkylation and Epoxidation Facilitated by a Recyclable Polymer-Supported Oxidant for the In-Flow Preparation of Diazo Compounds [J] . Nicolle Simon M., Hayes Christopher J., Moody Christopher J. Chemistry: A European journal . 2015,第12期

机译：可循环使用的聚合物支撑氧化剂在重氮化合物流式制备中的无卤卤杂原子烷基化和环氧化作用
2. #beta#-Oxy-#alpha#-diazo-carbonyl compounds. Part 6: Syntheiss and reactivity of 3-deoxy-2-diazo-esters derived from monosaccharides. Applications in the synthesis of 2-C-alkyl-KDO analogues and related compounds [J] . Francisco Sarabia, Fidel Jorge Lopez-Herrera Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry . 2001,第50期

机译：#beta＃-oxy-＃alpha＃-diazo-羰基化合物。第6部分：3-脱氧-2-二氮杂酯的合成和反应性来自单糖。在合成2-C-烷基-KDO类似物和相关化合物中的应用
3. BETA-OXY-ALPHA-DIAZO CARBONYL COMPOUNDS .4. REACTION WITH TRIETHYL BORANE - THE INFLUENCE OF THE OXY GROUP IN THE REGIO- AND STEREO-CONTROLLED ALKYLATION ON THE DIAZO CARBON [J] . Lopezherrera FJ., Sarabiagarcia F. Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry . 1995,第16期

机译：β-羟基-α-重氮羰基化合物.4。与三乙基硼烷反应-区域和立体控制的烷基中的氧自由基对重氮碳的影响
4. Preparation and Properties of CaO-Al_2O_3-SiO_2 Compounds for Recycling of Steel Slag, Paper Sludge and Coal Fly Ash [C] . Atsushi Kobayashi, Fahmida Gulshan, Yoshikazu Kameshima Recovery of Materials and Energy for Resource Efficiency World Conference . 2007

机译：CaO-Al_2O_3-SiO_2钢渣，纸污泥和煤粉煤灰回收的化合物的制备及性能
5. THE PREPARATION OF SOME 1-ALKYL-1,2,3,4-TETRAZOLE-5-THIOL AND 1-ARYL-1,2,3,4-TETRAZOLE-5-THIOL AND 3-ALKYLTETRAHYDRO-QUINAZOLINE-2-THIOL AND 3-ARYLTETRAHYDRO-QUINAZOLINE-2-THIOL COMPOUNDS AND THEIR INTERMEDIATES. [D] . ORTH, RONALD EMERSON. 1960

机译：制备一些1-烷基-1,2,3,4-四唑-5-硫醇和1-ARY-1,2,3,4-四唑-5-硫醇和3-烷基-喹啉-2-噻吩及3-芳基-喹啉-2-硫醇化合物及其中间体。
6. Visible-light-mediated Minisci C–H alkylation of heteroarenes with unactivated alkyl halides using O2 as an oxidant [O] . Jianyang Dong, Xueli Lyu, Zhen Wang, 2019

机译：可见光介导的杂芳烃的Minisci C–H烷基化与未活化的烷基卤化物使用氧气作为氧化剂
7. Preparation of Poly(diazo) Compounds as Precursors of Organo-Magnetic Materials by Utilizing Diazo Compound as Building Blocks [O] . Tetsuji Itoh, Katsuyuki Hirai, Hideo Tomioka 2005

机译：通过用作建筑物块作为有机磁性材料的前体制备聚（DiaZo）化合物的制备

Alkyl Halide-Free Heteroatom Alkylation and Epoxidation Facilitated by a Recyclable Polymer-Supported Oxidant for the In-Flow Preparation of Diazo Compounds

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