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Cyanoborohydride-Based Ionic Liquids as Green Aerospace Bipropellant Fuels

机译:基于氰基硼氢化物的离子液体作为绿色航空航天双推进剂燃料

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摘要

In propellant systems, the most common bipropellants are composed of two chemicals, a fuel (or reducer) and an oxidizer. Currently, the choices for propellant fuels rely mainly on hydrazine and its methylated derivatives, even though they are extremely toxic, highly volatile, sensitive to adiabatic compression (risk of detonation), and, therefore, difficult to handle. With this background, the search for alternative green propellant fuels has been an urgent goal of space science. In this study, a new family of cyanoborohydride- based ionic liquids (ILs) with properties and performances comparable to hydrazine derivatives were designed and synthesized. These new ILs as bipropellant fuels, have some unique advantages including negligible vapor pressure, ultra-short ignition delay (ID) time, and reduced synthetic and storage costs, thereby showing great application potential as environmentally friendly fuels in bipropellant formulations.
机译:在推进剂系统中,最常见的双推进剂由两种化学物质组成:燃料(或还原剂)和氧化剂。目前,推进剂燃料的选择主要取决于肼及其甲基化衍生物,尽管它们毒性极高,挥发性高,对绝热压缩敏感(有爆炸的危险),因此难以处理。在这种背景下,寻找替代绿色推进剂燃料一直是空间科学的紧迫目标。在这项研究中,设计并合成了一种新的基于氰基硼氢化物的离子液体(IL)系列,其性质和性能可与肼衍生物媲美。这些新型的ILs作为双推进剂燃料,具有一些独特的优势,包括可忽略的蒸气压,超短点火延迟(ID)时间以及降低的合成和储存成本,因此显示出在双推进剂配方中作为环保燃料的巨大应用潜力。

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