Tailoring the Solid-State Fluorescence Emission of BODIPY Dyes by meso Substitution

Kim Sungwoo; Bouffard Jean; Kim Youngmi

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Tailoring the Solid-State Fluorescence Emission of BODIPY Dyes by meso Substitution

机译：通过介观取代来调节BODIPY染料的固态荧光发射

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4,4-Difluoro-4-bora-3a, 4a-diaza-s-indacene (BODIPY) derivatives bearing varied substituents at the meso position (i.e., CF3, CH3, COOR, CHO, CN, Cl, iPr) were synthesized to elucidate the structure-property relationships that give rise to emissive J-aggregates. Several new BODIPY derivatives can be added to the previously reported 1,3,5,7-tetramethyl-8-trifluoromethyl derivative to the list of those forming J-aggregates, in addition to other dyes that are emissive in the solid state without forming J-aggregates.

机译：合成了在内消旋位置（即CF3，CH3，COOR，CHO，CN，Cl，iPr）带有不同取代基的4,4-二氟-4-硼3a，4a-二氮杂-s-茚并二烯（BODIPY）衍生物阐明引起发射J聚合的结构-属性关系。可以将几种新的BODIPY衍生物添加到先前报道的1,3,5,7-四甲基-8-三氟甲基衍生物中，以形成J聚集体，此外还可以固态释放的其他染料不形成J -汇总。

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《Chemistry: A European journal》 |2015年第48期|共7页
作者
Kim Sungwoo; Bouffard Jean; Kim Youngmi;
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aggregation-induced enhanced emission; BODIPY; J-aggregation; solid-state emission; vapor sensing;

机译：聚集诱导增强发射;BODIPY;J聚集;固态发射;蒸气感测;

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1. Tailoring the Solid-State Fluorescence Emission of BODIPY Dyes by meso Substitution [J] . Kim Sungwoo, Bouffard Jean, Kim Youngmi Chemistry: A European journal . 2015,第48期

机译：通过介观取代来调节BODIPY染料的固态荧光发射
2. Domino-like multi-emissions across red and near infrared from solid-state 2-/2,6-aryl substituted BODIPY dyes [J] . Dan Tian, Fen Qi, Huili Ma, Nature Communications . 2018,第1期

机译：固态2- / 2,6-芳基取代的BODIPY染料在红色和近红外光范围内出现类似Domino的多发射
3. Unprecedented one-pot sequential thiolate substitutions under mild conditions leading to a red emissive BODIPY dye 3,5,8-tris(PhS)-BODIPY [J] . Robinson I. Roacho, Alejandro Metta-Magana, Eduardo Pena-Cabrera, Organic & biomolecular chemistry . 2015,第4期

机译：在温和的条件下空前的一锅顺序硫醇盐取代，导致红色发光的BODIPY染料3,5,8-tris（PhS）-BODIPY
4. Electronic Structures and Theoretical Electronic Spcetra of meso-Phenyl and 3, 5-diaryl Substituted BODIPY Dyes [C] . Gaozhang Gou, Ling Shi, Bo Zhou, International Conference on Intelligent Mechanics and Materials Engineering . 2015

机译：中苯基的电子结构和理论电子Spcetra和3,5-二芳基取代的BOBIPY染料
5. Design and synthesis of NIR BODIPY dyes: Application for in vivo fluorescence imaging and photodynamic therapy [D] . Awuah, Samuel G. 2013

机译：NIR BODIPY染料的设计与合成：在体内荧光成像和光动力疗法中的应用
6. Domino-like multi-emissions across red and near infrared from solid-state 2-/26-aryl substituted BODIPY dyes [O] . Dan Tian, Fen Qi, Huili Ma, -1

机译：固态2- / 26-芳基取代的BODIPY染料在红色和近红外光范围内出现类似Domino的多发射
7. Modulation of singlet oxygen generation in halogenated BODIPY dyes by substitution at their: Meso position: Towards a solvent-independent standard in the vis region [O] . Epelde-Elezcano, N., Martínez-Martínez, V., Peña-Cabrera, E., 2016

机译：通过在卤代BODIPY染料上进行取代来调节其单线态氧的产生：中位：在vis区域内建立与溶剂无关的标准
8. I. Radiationless Transitions and Deuterium Effect on Luminescence Yields and Lifetimes of Some Aromatic Hydrocarbons. Ii. Temperature Dependence of Intersystem Crossing in Substituted Anthracenes. Iii. Charge-Transfer Interaction Between Saturated Hydrocarbons and Iodine. Iv. Delayed Fluorescence of Dyes in Rigid Organic Matrices [R] . Lim, E. C. 1966

机译：I.无辐射跃迁和氘对一些芳烃发光产率和寿命的影响。二。取代蒽中系统间交叉的温度依赖性。三。饱和烃与碘之间的电荷转移相互作用。四。刚性有机基质中染料的延迟荧光

Tailoring the Solid-State Fluorescence Emission of BODIPY Dyes by meso Substitution

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