Kinetic Resolution in the [2+2] Cycloaddition of Ketenes: An Experimental and Theoretical Study

Rulliere Pauline; Carret Sebastien; Milet Anne; Poisson Jean-Francois

首页> 外文期刊>Chemistry: A European journal >Kinetic Resolution in the [2+2] Cycloaddition of Ketenes: An Experimental and Theoretical Study

【24h】

Kinetic Resolution in the [2+2] Cycloaddition of Ketenes: An Experimental and Theoretical Study

机译：Ketenes的[2 + 2]环加成反应中的动力学拆分：实验和理论研究

获取原文

获取原文并翻译 | 示例

掌桥外文数据库（机构版） >>

开具论文收录证明 >>

文献代查 >>

页面导航

摘要
著录项
相似文献
相关主题

摘要

The kinetic resolution of Z and E olefins by [2+2] cycloaddition with ketenes allows the isolation of pure E olefin, as well as the synthesis of pure cis-cyclobutanones, starting from Z/E mixtures. A computational rationale for this kinetic difference is reported. The obtained difference of energy of activation matches with the experimental results.

机译：通过与烯酮的[2 + 2]环加成反应，Z和E烯烃的动力学拆分可从Z / E混合物开始分离纯E烯烃，以及合成纯顺式-环丁酮。报道了该动力学差异的计算原理。所获得的活化能差与实验结果相符。

著录项

来源
《Chemistry: A European journal》 |2015年第10期|共6页
作者
Rulliere Pauline; Carret Sebastien; Milet Anne; Poisson Jean-Francois;
展开▼
作者单位

展开▼
收录信息
原文格式 PDF
正文语种 eng
中图分类
关键词
cycloaddition; ketenes; kinetic resolution; olefins; stereochemistry;

机译：环加成;烯酮;动力学拆分;烯烃;立体化学;

相似文献

外文文献
中文文献
专利

1. Kinetic Resolution in the [2+2] Cycloaddition of Ketenes: An Experimental and Theoretical Study [J] . Rulliere Pauline, Carret Sebastien, Milet Anne, Chemistry: A European journal . 2015,第10期

机译：Ketenes的[2 + 2]环加成反应中的动力学拆分：实验和理论研究
2. Theoretical Study for the [2+2] Cycloaddition Reaction Mechanism of Ketenes and their Derivatives [J] . HAYDAR A. MOHAMMAD-SALIM, HASSAN H. ABDALLAH Oriental Journal of Chemistry: An International Research Journal of Pure & Applied Chemistry . 2019,第5期

机译：酮类及其衍生物[2 + 2]环加成反应机理的理论研究
3. Intramolecular competition between alkenes in ketene-alkene [2+2] cycloaddition. A theoretical study [J] . Ramirez-Galicia G, Rubio MF, Jimenez-Cruz F Journal of Molecular Structure. Theochem: Applications of Theoretical Chemistry to Organic, Inorganic and Biological Problems . 2006,第1a3期

机译：乙烯酮-烯烃[2 + 2]环加成反应中烯烃之间的分子内竞争。理论研究
4. An experimental and theoretical kinetic study of the reaction of OH radicals with 1,4-dioxane [C] . Fethi Khaled, Binod Raj Giri, Milan Szori, US Combustion Meeting . 2017

机译：用1,4-二恶烷的OH基团反应的实验与理论动力学研究
5. Theoretical studies of organic systems: Ruthenium catalyzed [2+2] cycloadditions and fluorine-19 NMR spectra of perfluoro-octanesulfonamides [D] . Liu, Peng 2006

机译：有机体系的理论研究：钌催化的[2 + 2]环加成反应和全氟辛烷磺酰胺的Fluor-19 NMR光谱
6. Dynamic Kinetic Resolution of Allylic Sulfoxides by Rh-Catalyzed Hydrogenation: A Combined Theoretical and Experimental Mechanistic Study [O] . Peter K. Dornan, Kevin G. M. Kou, K. N. Houk, -1

机译：Rh催化加氢动态烯丙基亚砜的动力学拆分：理论和实验机理的组合研究
7. Remote Substituent Effects in Ruthenium-Catalyzed 2+2 Cycloadditions: An Experimental and Theoretical Study [O] . -1

机译：钌催化的远程取代基效应2 + 2环加入：实验和理论研究

Kinetic Resolution in the [2+2] Cycloaddition of Ketenes: An Experimental and Theoretical Study

摘要

著录项

相似文献

相关主题

期刊订阅