Unique Hydrogen-Bonded Complex of Hydronium and Hydroxide Ions

Stapf Manuel; Seichter Wilhelm; Mazik Monika

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Unique Hydrogen-Bonded Complex of Hydronium and Hydroxide Ions

机译：独特的氢键结合的氢键和氢氧根离子

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H3O+ and OH-, formed by the self-ionization of two coordinating water molecules during the crystal growing of a host molecule [1,3,5-tris(hydroxymethyl)2,4,6-triethylbenzene (1)], could be effectively stabilized by hydrogen-bonding interactions with the preorganized hydroxy groups of three molecules of 1. The binding motifs observed in the complex (1)(3)H3O+HO- show remarkable similarity to those postulated for the hydrated hydronium and hydroxide ion complexes, which play important roles in various chemical, biological, and atmospheric processes, but their molecular structures are still not fully understood and remain a subject of intensive research.

机译：由主体分子[1,3,5-三（羟甲基）2,4,6-三乙苯（1）]晶体生长过程中两个配位水分子的自电离形成的H3O +和OH-可能是有效的通过与三个1分子的预组织羟基进行氢键相互作用而稳定。在配合物（1）（3）H3O + HO-中观察到的结合基序与水合水合氢氧根和氢氧根离子配合物所显示的相似性非常相似。在各种化学，生物和大气过程中起着重要作用，但它们的分子结构仍未完全理解，仍是深入研究的主题。

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《Chemistry: A European journal》 |2015年第17期|共5页
作者
Stapf Manuel; Seichter Wilhelm; Mazik Monika;
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hydrogen bonds; hydronium ion complexes; hydroxide ion complexes; preorganization; self-assembly; supramolecular chemistry;

机译：氢键氢氧根离子络合物氢氧根离子络合物预组织自组装超分子化学;

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1. Unique Hydrogen-Bonded Complex of Hydronium and Hydroxide Ions [J] . Stapf Manuel, Seichter Wilhelm, Mazik Monika Chemistry: A European journal . 2015,第17期

机译：独特的氢键结合的氢键和氢氧根离子
2. Comparison of CBS-QB3, CBS-APNO, G2, and G3 thermochemical predictions with experiment for formation of ionic clusters of hydronium and hydroxide ions complexed with water - art. no. 024302 [J] . Pickard FC, Pokon EK, Liptak MD, The Journal of Chemical Physics . 2005,第2期

机译：将CBS-QB3，CBS-APNO，G2和G3热化学预测值与与水络合的水合氢氧根离子和氢氧根离子的离子簇形成的实验进行比较。没有。 024302
3. A probable hydrogen-bonded meisenheimer complex: An unusually high S _NAr reactivity of nitroaniline derivatives with hydroxide ion in aqueous media [J] . Imoto M., Matsui Y., Takeda M., The Journal of Organic Chemistry . 2011,第15期

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4. Incorporation of Metal Ions into Hydrogen-Bonded Polymer Complex Film [C] . Rehan Kiran, Ali Altam, Chao Su, Donghua University;Sino-Africa international symposium on textiles and apparel;Bahir Dar University . 2018

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6. On the recombination of hydronium and hydroxide ions in water [O] . Ali Hassanali, Meher K. Prakash, Hagai Eshet, 2011

机译：关于水中水合氢离子和氢氧根离子的重组
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Unique Hydrogen-Bonded Complex of Hydronium and Hydroxide Ions

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