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The First One-Pot Synthesis of Metal-Organic Frameworks Functionalised with Two Transition-Metal Complexes

机译:用两个过渡金属配合物官能化的金属有机骨架的第一个一锅合成

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摘要

The synthesis of a metal-organic framework (UiO-67) functionalised simultaneously with two different transition metal complexes (Ir and Pd or Rh) through a one-pot procedure is reported for the first time. This has been achieved by an iterative modification of the synthesis parameters combined with characterisation of the resulting materials using different techniques, including X-ray absorption spectroscopy (XAS). The method also allows the first synthesis of UiO-67 with a very wide range of loadings (from 4 to 43 mol%) of an iridium complex ([IrCp*(bpydc)(Cl)Cl](2-); bpydc=2,2'-bipyridine-5,5'-dicarboxylate, Cp* = pentamethylcyclopentadienyl) through a pre-functionalisation methodology.
机译:首次报道了通过一锅法同时用两种不同的过渡金属配合物(Ir和Pd或Rh)官能化的金属有机骨架(UiO-67)的合成。这是通过使用不同的技术(包括X射线吸收光谱法(XAS))对合成参数进行迭代修改以及对所得材料进行表征来实现的。该方法还允许首次合成具有非常宽的负载范围(从4到43 mol%)的铱络合物([IrCp *(bpydc)(Cl)Cl](2-); bpydc = 2的UiO-67。 (2′-联吡啶-5,5′-二羧酸酯,Cp * =五甲基环戊二烯基)通过预官能化方法。

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