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首页> 外文期刊>Chemistry: A European journal >Chiral IminophosphoranesAn Emerging Class of Superbase Organocatalysts
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Chiral IminophosphoranesAn Emerging Class of Superbase Organocatalysts

机译：手性亚氨基正膦酸酯类一类新兴的超碱有机催化剂

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摘要

Chiral BrOnsted base catalysis is a fascinating and highly explored field of research. For many years catalysts based on chincona alkaloid chiral scaffolds have constituted privileged systems widely employed in numerous base-promoted organic transformations. Recently, a novel group of chiral base catalysts has been successfully introduced. The application of organosuperbases, namely cyclopropenimines, guanidines, and iminophosphoranes, as chiral catalysts is receiving increasing attention. The aim of this Concept article is to summarize recent progress in the field of chiral iminophosphorane superbase organocatalysis. Catalysts design, different approaches to their synthesis, and applications in asymmetric synthesis are outlined and discussed in detail.
机译：手性布朗斯台德碱催化是一个引人入胜且高度探索的研究领域。多年以来，基于chincona生物碱手性支架的催化剂已构成在许多碱促进的有机转化中广泛使用的特权系统。最近，已经成功地引入了一组新的手性碱催化剂。作为手性催化剂，有机超强碱，即环丙亚胺，胍和亚氨基正膦的应用越来越受到关注。本文的目的是总结手性亚氨基正膦超碱有机催化领域的最新进展。概述并详细讨论了催化剂的设计，不同的合成方法以及在不对称合成中的应用。

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