Bis[(dialkylamino)cyclopropenimine]-Stabilized P-III- and P-V-Centered Dications

Kozma Ygnes; Rust Joerg; Alcarazo Manuel

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Bis[(dialkylamino)cyclopropenimine]-Stabilized P-III- and P-V-Centered Dications

机译：双[（二烷基氨基）环丙亚胺]-稳定的P-III-和P-V-中心阳离子

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The treatment of bis[(dialkylamino)cyclopropenimines] with dihalophosphines in the presence of trimethylsilyl trifluoromethanesulfonate (TMSOTf) to form diimine-stabilized P-III-centered dications is reported. The structures of the new compounds were determined by using X-ray diffraction analysis and their donor abilities as ligands evaluated through electrochemical methods. Despite the two positive charges that they bear, these compounds depict intermediate behavior between that of phosphines and phosphites. The coordination of the [L2PR](2+) moiety to Au-I and Ag-I is also reported. Even more surprisingly, these phosphorus centers can be oxidized to the corresponding P-V dications in the presence of strong oxidants such as peroxides or XeF2.

机译：据报道，在三甲基甲硅烷基三氟甲磺酸盐（TMSOTf）存在下，用二卤代膦处理双[（（二烷基氨基）环丙啶胺]形成二亚胺稳定的以P-III为中心的药物。通过使用X射线衍射分析来确定新化合物的结构，并通过电化学方法评估它们作为配体的供体能力。尽管它们带有两个正电荷，这些化合物仍显示出膦和亚磷酸酯之间的中间行为。还报道了[L2PR]（2+）部分与Au-1和Ag-1的配位。甚至更令人惊讶的是，在强氧化剂如过氧化物或XeF2的存在下，这些磷中心可被氧化成相应的P-V指示。

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《Chemistry: A European journal》 |2015年第30期|共6页
作者
Kozma Ygnes; Rust Joerg; Alcarazo Manuel;
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正文语种 eng
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cations; electrochemistry; gold; ligand design; phosphorus;

机译：阳离子;电化学;金;配体设计;磷;

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1. Bis[(dialkylamino)cyclopropenimine]-Stabilized P-III- and P-V-Centered Dications [J] . Kozma Ygnes, Rust Joerg, Alcarazo Manuel Chemistry: A European journal . 2015,第30期

机译：双[（二烷基氨基）环丙亚胺]-稳定的P-III-和P-V-中心阳离子
2. Dication species stabilized by heteroazulenes: synthesis and properties of 1,3- and 1,4-bis[bis(2-oxo-2H-cyclohepta[b]furan-3-yl)methyliumyl]-, bis[bis(1,2-dihydro-N-methyl-2-oxocyclohepta[b]pyrrol-3-yl)methyliumyl]benzene, and their related dications [J] . Shin-ichi Naya and Makoto Nitta Journal of the Chemical Society, Perkin Transactions 2 . 2001,第3期

机译：杂azulenes稳定的阳离子种类：1,3-和1,4-双[双（2-氧代-2H-环庚[b]呋喃-3-基）甲基鎓]]，双[双（1,2） -二氢-N-甲基-2-氧代环庚[b]吡咯-3-基）甲基鎓基]苯及其相关药物
3. Dication species stabilized by heteroazulenes: synthesis and properties of 1,3- and 1,4-bis[bis(2-oxo-2H-cyclohepta[b]furan-3-yl)methyliumyl]-, bis[bis(1,2-dihydro-N-methyl-2-oxocyclohepta[b]pyrrol-3-yl)methyliumyl]ben zene, and their related dicatio [J] . Naya S., Nitta M. Journal of the Chemical Society. Perkin Transactions 2 . 2001,第3期

机译：杂唑稳定的阳离子物种：1,3-和1,4-双[双（2-氧代-2H-环庚[b]呋喃-3-基）甲基鎓基]-，双[双（1,2）的合成和性质-二氢-N-甲基-2-氧代环庚[b]吡咯-3-基）甲基鎓基]苯及其相关的鉴定
4. Synthesis and Fluorescence Properties of Macrocycles Containing Highly Twisted Bis(N,N’-dialkylamino)arenes [C] . Tomohisa Oizumi, Keisuke Ikeda, Keisuke Ikeda, 日本化学会春季年会講演予稿集 . 2018

机译：含有高扭曲双（n，n'-二烷基氨基）的宏依克的合成和荧光特性
5. Use of bis-phosphine platinum-dications as highly electrophilic catalysts for generation of intermediate carbocations in catalysis. [D] . Mullen, Charles A. 2007

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6. 17-Bis-(NN-dialkylamino)perylene Bisimides: Facile Synthesis and Characterization as Near-Infrared Fluorescent Dyes [O] . Kew-Yu Chen, Che-Wei Chang 2014

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7. Synthesis Efforts of Acyclic Bis(monoalkylamino)maleonitriles and Macrocyclic Bis(dialkylamino)maleonitriles as Fluorescent Probes for Cations and a New Colorimetric Copper(II) Chemodosimeter [O] . Thomas Schwarze, Eric Sperlich, Thomas Müller, 2021

机译：无环双（单烷基氨基）马来腈和宏环双（二烷基氨基）马来腈作为阳离子的荧光探针和新的比色铜（II）ChemodoImeter的合成努力
8. Tetrakis(dialkylamino)Cyclotetraphosphines and Bis(dialkylamino)Dihalobiphosphines [R] . King, R. B., Sadanani, N. D. 1985

机译：四（二烷基氨基）环四膦和双（二烷基氨基）二卤代双膦

Bis[(dialkylamino)cyclopropenimine]-Stabilized P-III- and P-V-Centered Dications

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