The First Lutetacyclopentadienes: Synthesis, Structure, and Diversified Insertion/C-H Activation Reactivity

Xu Ling; Wang Yu-Chen; Wei Junnian; Wang Yang; Wang Zitao; Zhang Wen-Xiong; Xi Zhenfeng

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The First Lutetacyclopentadienes: Synthesis, Structure, and Diversified Insertion/C-H Activation Reactivity

机译：第一种lutatecyclopentadienes：合成，结构和多样化的插入/ C H活化反应性。

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The first well-defined lutetacyclopentadienes are synthesised from pentamethylcyclopentadienyl lithium (Cp*Li), 1,4-dilithio-1,3-butadienes, and LuCl3. The lutetacyclopentadiene shows excellent reactivity towards some small molecules, such as pivalaldehyde, Se, carbon dioxide, and isonitrile to efficiently construct 3-, 5-, 7-, 8-, and 9-membered rare-earth metallacycles. Both monoinsertion and double-insertion of two Lu-C-sp2 bonds are observed. Specially, the reaction between lutetacyclopentadiene and isonitrile afforded [3,5,5]-fused metallacycles. The distinguished reactivity can be attributed to the highly ionic character and the cooperative reactivity of two Lu-C-sp2 bonds.

机译：由五甲基环戊二烯基锂（Cp * Li），1,4-二硫代-1,3-丁二烯和LuCl3合成了第一个定义明确的lutetacyclopentpentenes。 lutetacyclopentadiene对某些小分子（如新戊醛，Se，二氧化碳和异腈）显示出出色的反应活性，可有效构建3、5、7、8和9元稀土金属环。观察到两个Lu-C-sp2键的单插入和双插入。特别地，lutetacyclopentadiene和异腈之间的反应提供了[3,5,5]稠合的金属环。杰出的反应性可以归因于两个Lu-C-sp2键的高离子特性和协同反应性。

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来源
《Chemistry: A European journal》 |2015年第18期|共4页
作者
Xu Ling; Wang Yu-Chen; Wei Junnian; Wang Yang; Wang Zitao; Zhang Wen-Xiong; Xi Zhenfeng;
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正文语种 eng
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1; 4-dilithio-1; 3-butadienes; insertion reactions; metallacyclopentadienes; rare-earth metals;

机译：1;4-二硫代-1;3-丁二烯;插入反应;金属环戊二烯;稀土金属;

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1. The First Lutetacyclopentadienes: Synthesis, Structure, and Diversified Insertion/C-H Activation Reactivity [J] . Xu Ling, Wang Yu-Chen, Wei Junnian, Chemistry: A European journal . 2015,第18期

机译：第一种lutatecyclopentadienes：合成，结构和多样化的插入/ C H活化反应性。
2. A Two-Coordinate Iron(II) Imido Complex with NHC Ligation: Synthesis, Characterization, and Its Diversified Reactivity of Nitrene Transfer and C-H Bond Activation [J] . Cheng Jun, Liu Jian, Leng Xuebing, Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2019,第11期

机译：具有NHC结扎的双坐标铁（II）咪达络合物：合成，表征及其多元化反应性的硝基转移和C-H键活化
3. The carbene insertion methodology for the catalytic functionalization of unreactive hydrocarbons: No classical C-H activation, but efficient C-H functionalization [J] . Diaz-Requejo MM, Belderrain TR, Nicasio MC, Dalton transactions: An international journal of inorganic chemistry . 2006,第47期

机译：卡宾插入法用于未反应碳氢化合物的催化功能化：没有经典的C-H活化，但是有效的C-H官能化
4. CuO-Al_2O_3 mixed oxide material: synthesis, structure and catalytic behavior for C-H activation [C] . Y. N. TCHENAR, A. CHOUKCHOU-BRAHAM International Congress on Design and Modeling of Mechanical Systems . 2014

机译：CuO-Al_2O_3混合氧化物材料：C-H激活的合成，结构和催化行为
5. Synthesis and reactivity studies of late transition metal complexes relevant to C-H bond activation and functionalization [D] . Hanson, Susan Kloek 2007

机译：与C-H键活化和功能化有关的后期过渡金属配合物的合成和反应性研究
6. A Two-Coordinate Iron(II) Imido Complex with NHC Ligation:Synthesis Characterizationand Its Diversified Reactivity of Nitrene Transfer and C–HBond Activation [O] . Jun Cheng, Jian Liu, Xuebing Leng, -1

机译：具有NHC连接的二坐标铁（II）亚氨基配合物：合成表征转移和CH的硝化反应及其多样性债券激活
7. Rhodium(II)-catalyzed intramolecular C-H insertion α- to oxygen: reactivity, selectivity and applications to natural product synthesis [O] . Lombard Fanny, Coster Mark 2015

机译：铑（II）催化的分子内C-H插入氧中-反应性，选择性及其在天然产物合成中的应用

The First Lutetacyclopentadienes: Synthesis, Structure, and Diversified Insertion/C-H Activation Reactivity

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