'(Diphosphine)Nickel'-Catalyzed Negishi Cross-Coupling: An Experimental and Theoretical Study

Nicolas Emmanuel; Ohleier Alexia; DAccriscio Florian; Pecharman Anne-Frederique; Demange Matthieu; Ribagnac Philippe; Ballester Jorge; Gosmini Corinne; Mezailles Nicolas

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'(Diphosphine)Nickel'-Catalyzed Negishi Cross-Coupling: An Experimental and Theoretical Study

机译：“（二膦）镍”催化的根岸交叉偶联：实验和理论研究

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The use of a strongly donating (bis-dialkylphosphine)Ni fragment promotes the catalytic coupling of a large range of ArCl and ArZnCl derivatives under mild conditions. Stoichiometric mechanistic investigations and DFT calculations prove that a Ni-0/Ni-II cycle is operative in this system.

机译：在温和条件下，使用强供电的（双-二烷基膦）Ni片段可促进大量ArCl和ArZnCl衍生物的催化偶联。化学计量的机械学研究和DFT计算证明了Ni-0 / Ni-II循环在该系统中有效。

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《Chemistry: A European journal》 |2015年第21期|共5页
作者
Nicolas Emmanuel; Ohleier Alexia; DAccriscio Florian; Pecharman Anne-Frederique; Demange Matthieu; Ribagnac Philippe; Ballester Jorge; Gosmini Corinne; Mezailles Nicolas;
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正文语种 eng
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cross-coupling; dft; diphosphine ligands; mechanistic study; Negishi coupling; Ni catalysis;

机译：交叉偶联;dft;二膦配体;机理研究;Negishi偶联;Ni催化;

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1. "(Diphosphine)Nickel"-Catalyzed Negishi Cross-Coupling: An Experimental and Theoretical Study [J] . Nicolas Emmanuel, Ohleier Alexia, DAccriscio Florian, Chemistry: A European journal . 2015,第21期

机译：“（二膦）镍”催化的根岸交叉偶联：实验和理论研究
2. "(Diphosphine)Nickel"-Catalyzed Negishi Cross-Coupling: An Experimental and Theoretical Study [J] . Nicolas Emmanuel, Ohleier Alexia, DAccriscio Florian, Chemistry: A European journal . 2015,第21期

机译：“（二膦）镍”催化的根岸交叉偶联：实验和理论研究
3. Combined Theoretical and Experimental Studies of Nickel-Catalyzed Cross-Coupling of Methoxyarenes with Arylboronic Esters via C-O Bond Cleavage [J] . Schwarzer Martin C., Konno Ryosuke, Hojo Takayuki, Journal of the American Chemical Society . 2017,第30期

机译：镍催化甲氧芳烃与芳硼酸酯通过C-O键断裂的交叉偶联理论和实验研究
4. Theoretical Study of Nickel-catalyzed Arylcyanation of Alkynes [C] . Yu-ya Ohnishi, Yoshihide Nakao, Hirofumi Sato Symposium on Organometallic Chemistry . 2006

机译：炔烃镍催化芳基氰化的理论研究
5. An experimental and theoretical study of transient liquid phase bonding of nickel based materials [D] . Abdelfattah, Mohamed 2008

机译：镍基材料瞬态液相键合的实验和理论研究
6. Nickel-Catalyzed Negishi Cross-Coupling Reactions of Secondary Alkylzinc Halides and Aryl Iodides [O] . Amruta Joshi-Pangu, Madhu Ganesh, Mark R. Biscoe -1

机译：镍催化根岸交叉偶联二级烷基锌卤化物和芳基碘的反应
7. Experimental and theoretical studies on nickel-zinc-catalyzed cross-coupling of gem-dibromoalkenes with P(O)-H compounds [O] . Liu Liu, Lv Ye, Wu Yile, 2014

机译：镍-锌催化的宝石二溴烯烃与P（O）-H化合物交叉偶联的实验和理论研究

'(Diphosphine)Nickel'-Catalyzed Negishi Cross-Coupling: An Experimental and Theoretical Study

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