Gd-TEMDO: Design, Synthesis, and MRI Application

Boltjes Andre; Shrinidhi Annadka; van de Kolk Kees; Herdtweck Eberhardt; Domling Alexander

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Gd-TEMDO: Design, Synthesis, and MRI Application

机译：Gd-TEMDO：设计，合成和MRI应用

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A simple Ugi tetrazole multicomponent reaction allows the synthesis of a novel macrocyclic cyclen derivative with four appendant tetrazole arms in just two steps in excellent yields. This ligand, called TEMDO, turns out to have a high complexation affinity with lanthanoid metals. Here we describe the design, synthesis, solid-state structure, binding constant, and some MRI applications of the Gd-TEMDO complex as the first example of a congeneric family of oligo-amino tetrazoles.

机译：简单的Ugi四唑多组分反应可在两个步骤中以优异的产率合成具有四个附加的四唑臂的新型大环环素衍生物。该配体被称为TEMDO，结果证明与镧系金属具有很高的络合亲和力。在这里，我们描述Gd-TEMDO配合物的设计，合成，固态结构，结合常数和某些MRI应用，作为低聚氨基四唑类同族的第一个例子。

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《Chemistry: A European journal》 |2016年第22期|共6页
作者
Boltjes Andre; Shrinidhi Annadka; van de Kolk Kees; Herdtweck Eberhardt; Domling Alexander;
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正文语种 eng
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gadolinium; macrocyclic ligands; magnetic resonance imaging; multicomponent reactions; oligoamino tetrazole;

机译：大环配体;磁共振成像;多组分反应;低聚氨基四唑;

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6. Gd-TEMDO: Design synthesis and MRI application [O] . André Boltjes, Dr Annadka Shrinidhi, C.W.A. Kees van de Kolk, -1

机译：Gd-TEMDO：设计合成和MRI应用
7. Gd-TEMDO: Design, Synthesis, and MRI Application [O] . Boltjes, André, Shrinidhi, Annadka, van de Kolk, Kees, 2016

机译：Gd-TEMDO：设计，合成和MRI应用

Gd-TEMDO: Design, Synthesis, and MRI Application

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