Tether-Directed Bisfunctionalization Reactions of C-60 and C-70

Ceron Maira R.; Izquierdo Marta; Pi Yunhong; Atehortua Sandra L.; Echegoyen Luis

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Tether-Directed Bisfunctionalization Reactions of C-60 and C-70

机译：C-60和C-70的系链定向双官能化反应

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Four easily isolable regio- and stereoselective bis-adducts of C-60 and C-70, as well as a new C-70-dumbbell derivative, have been synthesized by using two different bismalonate tethered moieties. The derivatives that possess relatively long-tethered moieties show highly symmetric addition patterns, as evidenced by spectroscopic measurements, whereas the derivatives possessing the shorter-tethered moiety exhibit interesting addition patterns on C-60 and C-70.

机译：通过使用两个不同的双丙二酸酯系链部分，合成了C-60和C-70的四个易于分离的区域选择性和立体选择性双加合物，以及一个新的C-70哑铃衍生物。如通过光谱测量所证实的，具有相对较长的束缚部分的衍生物显示出高度对称的加成模式，而具有较短的束缚部分的衍生物在C-60和C-70上表现出令人感兴趣的加成模式。

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来源
《Chemistry: A European journal》 |2015年第21期|共5页
作者
Ceron Maira R.; Izquierdo Marta; Pi Yunhong; Atehortua Sandra L.; Echegoyen Luis;
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正文语种 eng
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bis-adducts; cycloaddition; fullerenes; regioselectivity; stereoselectivity;

机译：双加合物;环加成;富勒烯;区域选择性;立体选择性;

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1. Tether-Directed Bisfunctionalization Reactions of C-60 and C-70 [J] . Ceron Maira R., Izquierdo Marta, Pi Yunhong, Chemistry: A European journal . 2015,第21期

机译：C-60和C-70的系链定向双官能化反应
2. The addition reactions between N-heterocyclic carbenes and fullerenes (C-60 and C-70): a density functional study [J] . Li Ming-Chung, Su Ming-Der Theoretical chemistry accounts . 2015,第3期

机译：N-杂环卡宾与富勒烯（C-60和C-70）之间的加成反应：密度泛函研究
3. Ozone reaction with carbon nanostructures 1: Reaction between solid C-60 and C-70 fullerenes and ozone [J] . Cataldo F Journal of nanoscience and nanotechnology . 2007,第4a5期

机译：具有碳纳米结构的臭氧反应1：固态C-60和C-70富勒烯与臭氧之间的反应
4. Chemoselective Synthesis of Novel Macrocyclic Polyether 60 Fullerene bis- and tris-Adducts by Tether-Directed Chemistry and Study of their Complexation Behavior with Alkali Metal Cations [C] . Zhiguo Zhou, David I. Schuster, Stephen R. Wilson International Symposium on Fullerenes, Nanotubes, and Carbon Nanoclusters, May 12-17, 2002, Philadelphia . 2002

机译：系链导向化学化学选择性合成新型大环聚醚60富勒烯双-和三-加合物及其与碱金属阳离子的络合行为研究
5. Synthesis of new calix[4]arenes and calix[4]naphthalenes via Sonogashira reactions, photochemically -induced reactions and [2+2] fragment condensation reactions [D] . Al-Saraierh, Hassan 2007

机译：通过Sonogashira反应，光化学诱导的反应和[2 + 2]片段缩合反应合成新的杯[4]芳烃和杯[4]萘
6. Synthesis of chiral α-trifluoromethyl alcohols and ethers via enantioselective Hiyama cross-couplings of bisfunctionalized electrophiles [O] . Andrii Varenikov, Mark Gandelman -1

机译：双官能化亲电试剂的对映选择性Hiyama交叉偶联合成手性α-三氟甲基醇和醚
7. ECSTM study of adsorption of C-60, C-70, C-86 and Y@C-82 on Au(111) [O] . Su GuiJin, Jia ManKe, Gan LiHua, 2010

机译：ECSTM研究C-60，C-70，C-86和Y @ C-82在Au（111）上的吸附

Tether-Directed Bisfunctionalization Reactions of C-60 and C-70

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