Modulating the Nucleated Self-Assembly of Tri-beta(3)-Peptides Using Cucurbit[n]urils

Satav Tushar; Korevaar Peter; de Greef Tom F. A.; Huskens Jurriaan; Jonkheijm Pascal

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Modulating the Nucleated Self-Assembly of Tri-beta(3)-Peptides Using Cucurbit[n]urils

机译：调制使用葫芦[n] urils的Tri-beta（3）肽有核自组装。

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The modulation of the hierarchical nucleated self-assembly of tri-beta(3)-peptides has been studied. beta(3)-Tyrosine provided a handle to control the assembly process through host-guest interactions with CB[7] and CB[8]. By varying the cavity size from CB[7] to CB[8] distinct phases of assembling tri-beta(3)-peptides were arrested. Given the limited size of the CB[7] cavity, only one aromatic beta(3)-tyrosine can be simultaneously hosted and, hence, CB[7] was primarily acting as an inhibitor of self-assembly. In strong contrast, the larger CB[8] can form a ternary complex with two aromatic amino acids and hence CB[8] was acting primarily as cross-linker of multiple fibers and promoting the formation of larger aggregates. General insights on modulating supramolecular assembly can lead to new ways to introduce functionality in supramolecular polymers.

机译：Tri-beta（3）肽的分层有核自组装的调制进行了研究。 beta（3）-酪氨酸通过与CB [7]和CB [8]的来宾-来宾相互作用提供了控制组装过程的手柄。通过从CB [7]到CB [8]改变腔体的大小，可以阻止组装三β（3）肽的不同相。鉴于CB [7]腔的大小有限，只能同时容纳一个芳香族β（3）-酪氨酸，因此CB [7]主要起自组装抑制剂的作用。与之形成强烈反差的是，较大的CB [8]可以与两个芳香族氨基酸形成三元络合物，因此CB [8]主要充当多根纤维的交联剂并促进较大聚集体的形成。关于调节超分子组装的一般见解可以导致在超分子聚合物中引入功能的新方法。

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《Chemistry: A European journal》 |2016年第36期|共5页
作者
Satav Tushar; Korevaar Peter; de Greef Tom F. A.; Huskens Jurriaan; Jonkheijm Pascal;
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正文语种 eng
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cooperativity; cucurbitnurils; host-guest systems; self-assembly;

机译：合作性;葫芦丝;主客系统;自组装;

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1. Modulating the Nucleated Self-Assembly of Tri-beta(3)-Peptides Using Cucurbit[n]urils [J] . Satav Tushar, Korevaar Peter, de Greef Tom F. A., Chemistry: A European journal . 2016,第36期

机译：调制使用葫芦[n] urils的Tri-beta（3）肽有核自组装。
2. Exploring cucurbit[6]uril-peptide interactions in the solid state: crystal structure of cucurbit[6]uril complexes with glycyl-containing dipeptides [J] . Danylyuk Oksana CrystEngComm . 2017,第28期

机译：探索葫芦肽[6]固态中的尿素肽相互作用：含有含糖糖的二肽的葫芦晶体结构[6]尿嘧啶
3. Structural Stabilities and Self-Assembly of Cucurbit[n]uril (n = 4-7) and Decamethylcucurbit[n]uril (n = 4-6): A Theoretical Study [J] . Kyung Seok Oh, Jungjoo Yoon, Kwang S.Kim The journal of physical chemistry, B. Condensed matter, materials, surfaces, interfaces & biophysical . 2001,第40期

机译：葫芦[n] uril（n = 4-7）和十甲基葫芦[n] uril（n = 4-6）的结构稳定性和自组装：理论研究
4. Binding Selectivity of Cucurbit5uril (CB5) and Substituted Cucurbit5uril For Anions in the Gas Phase [C] . Jiewen Shen, David V. Dearden ASMS Conference on Mass Spectrometry and Allied Topics . 2015

机译：CuCurbit 5 URIL（CB5）和取代的葫芦5 URIN用于气相中的阴离子的结合选择性
5. Self-assembly of dendrimers and cucurbit[n]uril complexes [D] . Wang, Wei 2008

机译：树状聚合物和葫芦[n] uril复合物的自组装
6. Orthogonal self-assembly of an organoplatinum(II) metallacycle and cucurbit8uril that delivers curcumin to cancer cells [O] . Sougata Datta, Santosh K. Misra, Manik Lal Saha, 2018

机译：有机铂（II）金属环和葫芦8尿素的正交自组装将姜黄素递送至癌细胞
7. Exploring cucurbit6uril–peptide interactions in the solid state: crystal structure of cucurbit6uril complexes with glycyl-containing dipeptides [O] . Oksana Danylyuk 2017

机译：探索葫芦肽6固态中的尿素肽相互作用：葫芦晶体结构6尿嘧啶络合物与含甘氨酸的二肽

Modulating the Nucleated Self-Assembly of Tri-beta(3)-Peptides Using Cucurbit[n]urils

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