Cyclic (Alkyl)(Amino)Carbene Complexes of Rhodium and Nickel and Their Steric and Electronic Parameters

Paul Ursula S. D.; Sieck Carolin; Haehnel Martin; Hammond Kai; Marder Todd B.; Radius Udo

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Cyclic (Alkyl)(Amino)Carbene Complexes of Rhodium and Nickel and Their Steric and Electronic Parameters

机译：铑和镍的环状（烷基）（氨基）碳配合物及其立体和电子参数

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N-heterocyclic carbenes (NHCs) and cyclic (alkyl)-(amino)carbenes (CAACs) are of great interest, as their electronic and steric properties provide a unique class of ligands and organocatalysts. Herein, substitution reactions involving novel carbonyl complexes of rhodium and nickel were studied to provide a deeper understanding of the fundamental electronic factors characterizing CAAC(methyl), which were compared with the large array of data available for NHC and sterically more demanding CAAC ligands.

机译：N-杂环卡宾（NHC）和环状（烷基）-（氨基）碳烯（CAAC）引起人们极大的兴趣，因为它们的电子和空间特性提供了独特的一类配体和有机催化剂。在本文中，研究了涉及铑和镍的新型羰基配合物的取代反应，以更深刻地理解表征CAAC（甲基）的基本电子因子，并将其与NHC和空间上要求更高的CAAC配体的大量数据进行了比较。

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来源
《Chemistry: A European journal》 |2016年第31期|共10页
作者
Paul Ursula S. D.; Sieck Carolin; Haehnel Martin; Hammond Kai; Marder Todd B.; Radius Udo;
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正文语种 eng
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carbene ligands; electronic structure; nickel; rhodium; steric hindrance;

机译：卡宾配体;电子结构;镍;铑;位阻;

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1. Cyclic (Alkyl)(Amino)Carbene Complexes of Rhodium and Nickel and Their Steric and Electronic Parameters [J] . Paul Ursula S. D., Sieck Carolin, Haehnel Martin, Chemistry: A European journal . 2016,第31期

机译：铑和镍的环状（烷基）（氨基）碳配合物及其立体和电子参数
2. Iron(II), cobalt(II), and nickel(II) complexes of a cyclic (alkyl)(amino)carbene [J] . Pelties S., Wolf R. Zeitschrift fur Anorganische und Allgemeine Chemie . 2013,第14期

机译：环状（烷基）（氨基）卡宾的铁（II），钴（II）和镍（II）配合物
3. Electronic Structure and Slow Magnetic Relaxation of Low-Coordinate Cyclic Alkyl(amino) Carbene Stabilized Iron(Ⅰ) Complexes [J] . Prinson P. Samuel, Kartik Chandra Mondal, Nurul Amin Sk, Journal of the American Chemical Society . 2014,第34期

机译：低配位环状烷基（氨基）碳稳定铁（Ⅰ）配合物的电子结构和慢磁弛豫
4. Bifunctional Selective Hydrosilylation of Terminal Alkynes by Bis(carbene)Iridium(III)and Rhodium(III)Complexes [C] . Luis A.Oro Annual Saudi-Japan Symposium on Technology in Petroleum Refining and Petrochemicals . 2018

机译：双（卡宾烯）铱（III）和铑（III）配合物的末端炔烃的双官能选择性氢化硅烷化
5. Reactivity of bis(amino)cyclopropenylidenes (BACs) and cyclic (alkyl)(amino)carbenes (CAACs): Coordination chemistry, catalysis, and small molecule activation. [D] . Kuchenbeiser, Glenn Richard. 2009

机译：双（氨基）环丙烯基（BAC）和环状（烷基）（氨基）卡宾（CAAC）的反应性：配位化学，催化和小分子活化。
6. Mechanistic Understanding of the Heterogeneous Rhodium-Cyclic(Alkyl)(Amino)Carbene-Catalyzed (Fluoro-)Arene Hydrogenation [O] . Daniel Moock, Mario P. Wiesenfeldt, Matthias Freitag, -1

机译：对异质铑环的机械理解（烷基）（氨基）碳催化的（氟）芳烃加氢
7. Synthesis, structure and cytotoxicity of cyclic (alkyl)(amino) carbene and acyclic carbene complexes of group 11 metals [O] . Benoît Bertrand, Alexander S. Romanov, Mark Brooks, 2017

机译：环状（烷基）（氨基）卡宾和11族金属环纤维络合物的合成，结构和细胞毒性
8. Activation Parameters for Rotation about a Metal-Carbon Bond from Temperature Dependent Proton N.m.r. Spectra of Rhodium Carbene Complexes. [R] . Doyle, M. J., Lappert, M. F. 1974

机译：从温度依赖的质子N.m.r.关于金属 - 碳键旋转的活化参数。铑卡宾配合物的光谱。

Cyclic (Alkyl)(Amino)Carbene Complexes of Rhodium and Nickel and Their Steric and Electronic Parameters

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