A Highly Water-Tolerant Magnesium(II) Coordination Polymer Derived from a Flexible Layered Structure

Ochi Rika; Noro Shin-ichiro; Kamiya Yuichi; Kubo Kazuya; Nakamura Takayoshi

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A Highly Water-Tolerant Magnesium(II) Coordination Polymer Derived from a Flexible Layered Structure

机译：柔性层状结构衍生的高耐水镁（II）配位聚合物

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摘要

A two-dimensional (2D) layered Mg-II coordination polymer (CP) with a high tolerance for H2O was designed, synthesised, and crystallographically characterised. The synthesis was achieved by the introduction of a flexible 2D layered structure composed of MgII ions and isonicotinate N-oxide ligands. Owing to its high H2O tolerance, the obtained 2D layered structure has the flexibility to repeatedly adsorb a large amount of H2O associated with interlayer expansion and enable the removal of H2O from a H2O/2-propanol mixed vapour. These results indicate that the CP could be an excellent dehydrating agent.

机译：设计，合成和结晶表征了具有高H2O耐受性的二维（2D）层状Mg-II配位聚合物（CP）。通过引入由MgII离子和异烟酸酯N-氧化物配体组成的2D柔性层状结构，可以实现合成。由于其高的H 2 O耐受性，所获得的2D层状结构具有灵活地重复吸附与层间膨胀相关的大量H 2 O并且能够从H 2 O / 2-丙醇混合蒸气中去除H 2 O的灵活性。这些结果表明CP可能是极好的脱水剂。

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《Chemistry: A European journal》 |2016年第31期|共6页
作者
Ochi Rika; Noro Shin-ichiro; Kamiya Yuichi; Kubo Kazuya; Nakamura Takayoshi;
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正文语种 eng
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adsorption; host-guest systems; layered compounds; ligand design; microporous materials;

机译：吸附;客体系统;层状化合物;配体设计;微孔材料;

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1. A Highly Water-Tolerant Magnesium(II) Coordination Polymer Derived from a Flexible Layered Structure [J] . Ochi Rika, Noro Shin-ichiro, Kamiya Yuichi, Chemistry: A European journal . 2016,第31期

机译：柔性层状结构衍生的高耐水镁（II）配位聚合物
2. Coordination polymers from a highly flexible alkyldiamine-derived ligand: structure, magnetism and gas adsorption studies [J] . Hawes Chris S., Chilton Nicholas F., Moubaraki Boujemaa, Dalton transactions: An international journal of inorganic chemistry . 2015,第40期

机译：高柔性烷基二胺衍生配体的配位聚合物：结构，磁性和气体吸附研究
3. Synthesis and Crystal Structure of a Novel 3D Magnesium(II) Coordination Polymer Constructed by Flexible Benzene-1,4-dioxyacetate [J] . GAO Shan, HUO Li-Hua, CHENG Xiao-Li, Chinese Journal of Structural Chemistry . 2005,第6期

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4. The Role of Magnesium(II)Salt Precursor in Controlling the Structure of Coordination Polymers based on Magnesium(II)and benzene 1,3,5-tricarboxylic acid [C] . W W Lestari, R A Tedra, T H Novita International Conference on Advanced Materials for Better Future . 2019

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5. Highly structured and surface modified poly(epsilon-caprolactone) scaffolds derived from co-continuous polymer blends for bone tissue engineering. [D] . Mehr, Nima Ghavidel. 2014

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6. Self-Assembly of 1D/2D Hybrid Nanostructures Consisting of a Cd(II) Coordination Polymer and NiAl-Layered Double Hydroxides [O] . Gonzalo Abellán, Pilar Amo-Ochoa, José Luis G. Fierro, 2016

机译：Cd（II）配位聚合物和NiAl层状双氢氧化物组成的1D / 2D杂化纳米结构的自组装
7. Dicarboxylate-controlled three Zn(II) coordination polymers incorporating flexible 1,2-bis(imidazol-1 '-yl)ethane ligand: Syntheses, structures, thermal stabilities and photoluminescent properties [O] . Hong-Jun Hao, 郝红君, Di Sun, 2012

机译：二羧酸盐控制的三种Zn（II）配位聚合物，结合了灵活的1,2-双（咪唑-1'-基）乙烷配体：合成，结构，热稳定性和光致发光性能
8. Inorganic Coordination Polymers. XVIII. Observations on Brittle and Flexible Films of (Cr((OP(CH3)(C6H5)O)2)(OP((C8H17)2)O))x. [R] . nannelli, piero gillman, h. d. 1975

机译：无机配位聚合物。十八。观察脆性和柔性薄膜（Cr（（Op（CH3）（C6H5）O）2）（Op（（C8H17）2）O））x。

A Highly Water-Tolerant Magnesium(II) Coordination Polymer Derived from a Flexible Layered Structure

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