Copper-Based Photosensitisers in Water Reduction: A More Efficient In Situ Formed System and Improved Mechanistic Understanding

Lennox Alastair J. J.; Fischer Steffen; Jurrat Mark; Luo Shu-Ping; Rockstroh Nils; Junge Henrik; Ludwig Ralf; Beller Matthias

首页> 外文期刊>Chemistry: A European journal >Copper-Based Photosensitisers in Water Reduction: A More Efficient In Situ Formed System and Improved Mechanistic Understanding

【24h】

Copper-Based Photosensitisers in Water Reduction: A More Efficient In Situ Formed System and Improved Mechanistic Understanding

机译：铜基光敏剂在减水中的应用：更高效的原位形成系统和增强的机理理解

获取原文

获取原文并翻译 | 示例

掌桥外文数据库（机构版） >>

开具论文收录证明 >>

文献代查 >>

页面导航

摘要
著录项
相似文献
相关主题

摘要

The reduction of water has been achieved through a non-noble-metal-based homogeneous catalyst system that is formed in situ. Optimisation of the ligand quantities increased catalyst turnover numbers compared to preformed complexes. Mechanistic studies confirm a heteroleptic Cu complex as the active photosensitiser (PS) and an in situ formed Fe-phosphido dimer complex as the water reduction catalyst. The in situ method has been used to screen a range of ligands for the active PS, which has led to the identification a number of structural features important to longevity and performance.

机译：通过原位形成的基于非贵金属的均相催化剂体系已经实现了水的减少。与预形成的配合物相比，配体数量的优化提高了催化剂的转化率。机理研究证实，杂铜Cu络合物可作为活性光敏剂（PS），而原位形成的Fe磷酸二聚体络合物可作为减水催化剂。原位方法已用于筛选活性PS的一系列配体，这导致鉴定出许多对寿命和性能至关重要的结构特征。

著录项

来源
《Chemistry: A European journal》 |2016年第4期|共6页
作者
Lennox Alastair J. J.; Fischer Steffen; Jurrat Mark; Luo Shu-Ping; Rockstroh Nils; Junge Henrik; Ludwig Ralf; Beller Matthias;
展开▼
作者单位

展开▼
收录信息
原文格式 PDF
正文语种 eng
中图分类
关键词
copper; homogeneous catalysis; photocatalysis; reaction mechanisms; reduction;

机译：铜;均相催化;光催化;反应机理;还原;

相似文献

外文文献
中文文献
专利

1. Copper-Based Photosensitisers in Water Reduction: A More Efficient In Situ Formed System and Improved Mechanistic Understanding [J] . Lennox Alastair J. J., Fischer Steffen, Jurrat Mark, Chemistry: A European journal . 2016,第4期

机译：铜基光敏剂在减水中的应用：更高效的原位形成系统和增强的机理理解
2. Highly-efficient and autocatalytic reduction of NaHCO3 into formate by in situ hydrogen from water splitting with metal/metal oxide redox cycle [J] . Guodong Yao, Jia Duo, Binbin Jin, 天然气化学（英文版） . 2017,第005期

机译：通过金属/金属氧化物氧化还原循环将水分解后的原位氢高效自动催化将NaHCO3还原成甲酸酯
3. Highly-efficient and autocatalytic reduction of NaHCO3 into formate by in situ hydrogen from water splitting with metal/metal oxide redox cycle [J] . Guodong Yao, Jia Duo, Binbin Jin, 能源化学：英文版 . 2017,第005期

机译：通过金属/金属氧化物氧化还原循环将水分解后的原位氢高效自动催化将NaHCO3还原成甲酸酯
4. Data mining and relationship analysis of water distribution system databases for improved understanding of operations performance [C] . D.M. Unwin, J.B. Boxall, A.J. Saul International Conference on Computing and Control for the Water Industry Sep 15-17, 2003 London, UK . 2003

机译：供水系统数据库的数据挖掘和关系分析，以提高对运营绩效的了解
5. Mechanistic studies for improved understanding of low salinity waterflooding based enhanced oil recovery and potential application to the Alaskan North Slope reservoirs. [D] . Chavan, Mukul N. 2015

机译：为提高对低盐度注水的认识而进行的机理研究，以提高采收率和在阿拉斯加北坡油藏中的潜在应用。
6. Mechanistic Systems Modeling to Improve Understanding and Prediction of Cardiotoxicity Caused by Targeted Cancer Therapeutics [O] . Jaehee V. Shim, Bryan Chun, Johan G. C. van Hasselt, 2017

机译：机械系统建模以提高对靶向癌症治疗药物引起的心脏毒性的理解和预测
7. Copper-Based Photosensitisers in Water Reduction: A More Efficient In Situ Formed System and Improved Mechanistic Understanding [O] . Alastair J. J. Lennox, Steffen Fischer, Mark Jurrat, 2015

机译：水减少铜的光敏仪：更有效地原位形成的系统和改善的机械理解
8. Improved Understanding of Fenton-like Reactions for the In Situ Remediation of Contaminated Groundwater Including Treatment of Sorbed Contaminants and Destruction of DNAPLs [R] . Watts, R. J. , Loge, F. , Teel, A. L. 2006

机译：改善对Fenton样反应的理解，对污染地下水进行原位修复，包括处理吸附污染物和破坏DNapLs

Copper-Based Photosensitisers in Water Reduction: A More Efficient In Situ Formed System and Improved Mechanistic Understanding

摘要

著录项

相似文献

相关主题

期刊订阅