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Modification of the Solution Behavior of Pd12L24 Metal-Organic Nanocages via PEGylation

机译:通过PEG化修饰Pd12L24金属有机纳米笼的溶液行为

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摘要

The dilute solutions behaviors of Pd12L24 metal-organic nanocage and its two PEGylated derivatives are explored. The basic nanocages can self-assemble into vesicle-like blackberry structures in polar solvents via counter-ion-mediated attraction, whereas the PEGylated nanocages always stay as discrete ions under the same conditions, demonstrating that the PEGylation can improve the stability of the single nanocages. In addition, larger nanocages are found to self-assemble in less polar solvents.
机译:探索了Pd12L24金属-有机纳米笼及其两种聚乙二醇化衍生物的稀溶液行为。基本的纳米笼可以通过反离子介导的吸引作用在极性溶剂中自组装成囊状黑莓结构,而聚乙二醇化的纳米笼在相同条件下始终以离散离子形式存在,这表明聚乙二醇化可以提高单个纳米笼的稳定性。 。另外,发现较大的纳米笼可以在极性较小的溶剂中自组装。

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