BrOnsted Acid-Mediated Hydrative Arylation of Unactivated Alkynes

Kaiser Daniel; Veiros Luis F.; Maulide Nuno

首页> 外文期刊>Chemistry: A European journal >BrOnsted Acid-Mediated Hydrative Arylation of Unactivated Alkynes

【24h】

BrOnsted Acid-Mediated Hydrative Arylation of Unactivated Alkynes

机译：布朗斯台德酸介导的未活化炔烃的氢化芳构化

获取原文

获取原文并翻译 | 示例

掌桥外文数据库（机构版） >>

开具论文收录证明 >>

文献代查 >>

页面导航

摘要
著录项
相似文献
相关主题

摘要

The BrOnsted acid-mediated reaction of unactivated alkynes with aryl sulfoxides leads to simultaneous hydration and intermolecular C-C bond formation. This solvent- and metal-free transformation directly delivers -arylated carbonyl compounds as the products of a formal hydrative arylation in an atom-economical manner. The products bear useful synthetic handles for further functionalization.

机译：未活化的炔烃与芳基亚砜的布朗斯台德酸介导的反应导致同时水合和分子间C-C键形成。这种无溶剂和无金属的转化以原子经济的方式直接递送芳基化芳基化产物的芳基化羰基化合物。该产品带有有用的合成手柄，可以进一步功能化。

著录项

来源
《Chemistry: A European journal》 |2016年第14期|共6页
作者
Kaiser Daniel; Veiros Luis F.; Maulide Nuno;
展开▼
作者单位

展开▼
收录信息
原文格式 PDF
正文语种 eng
中图分类
关键词
alkynes; arylation; organic chemistry; rearrangement; sulfoxides;

机译：炔烃;芳基化;有机化学;重排;亚砜;

相似文献

外文文献
中文文献
专利

1. BrOnsted Acid-Mediated Hydrative Arylation of Unactivated Alkynes [J] . Kaiser Daniel, Veiros Luis F., Maulide Nuno Chemistry: A European journal . 2016,第14期

机译：布朗斯台德酸介导的未活化炔烃的氢化芳构化
2. BrOnsted Acid-Mediated Hydrative Arylation of Unactivated Alkynes [J] . Kaiser Daniel, Veiros Luis F., Maulide Nuno Chemistry: A European journal . 2016,第14期

机译：布朗斯台德酸介导的未活化炔烃的氢化芳构化
3. Iron(III)-Catalyzed Hydration of Unactivated Internal Alkynes in Weak Acidic Medium, under Lewis Acid-Assisted Bronsted Acid Catalysis [J] . Antenucci Achille, Flamini Piergiorgio, Fornaiolo Marco Valerio, Advanced synthesis & catalysis . 2019,第19期

机译：铁（III） - 在Lewis酸辅助富酸酸催化下，在弱酸性介质中催化未激活的内部炔醇的催化水合
4. Palladium-Catalyzed Gross-Addition of Silylacetylenes to Unactivated Alkynes [C] . Naofumi Tsukada, Satoshi Ninomiya, Yoshimi Aoyama Symposium on Organometallic Chemistry . 2007

机译：钯 - 催化的甲硅烷乙烯基的总加入甲硅烷基乙烯基到未激活的炔烃
5. Palladium-Catalyzed Alkylation, Arylation and Dehydrogenation of Unactivated Carbon-Hydrogen bonds. Syntheses of the Tetracyclic Aminoquinone Moiety of Marmycin A, (+/-)-Nosyberkol (Isotuberculosinol, Revised Structure of Edaxadiene), and (+/-)-Tuberculosinol. [D] . Maugel, Nathan L. 2011

机译：钯催化未活化的碳氢键的烷基化，芳基化和脱氢。 Marmycin A，（+/-）-Nosyberkol（异丁香醇，Edaxadiene的结构经过修正）和（+/-）-Tuberculosinol的四环氨基醌部分的合成。
6. Iodine-mediated hydration of alkynes on keto-functionalized scaffolds: mechanistic insight and the regiospecific hydration of internal alkynes [O] . Zachary Lee, Brandon R Jones, Nyochembeng Nkengbeza, 2019

机译：碘在酮官能化支架上介导的炔烃水合：机理研究和内部炔烃的区域特异性水合
7. Catalytic hydration of alkynes over bronsted acid sites developed on halide clusters [O] . Kamiguchi Satoshi, Takahashi Ikuko, Kondo Kunihiko, 2008

机译：在卤化物簇上形成的布朗斯台德酸位上炔烃的催化水合

BrOnsted Acid-Mediated Hydrative Arylation of Unactivated Alkynes

摘要

著录项

相似文献

相关主题

期刊订阅