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Renewability is not Enough: Recent Advances in the Sustainable Synthesis of Biomass-Derived Monomers and Polymers

机译:可再生性还不够:生物质衍生的单体和聚合物可持续合成的最新进展

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摘要

Taking advantage of the structural diversity of different biomass resources, recent efforts were directed towards the synthesis of renewable monomers and polymers, either for the substitution of petroleum-based resources or for the design of novel polymers. Not only the use of biomass, but also the development of sustainable chemical approaches is a crucial aspect for the production of sustainable materials. This review discusses the recent examples of chemical modifications and polymerizations of abundant biomass resources with a clear focus on the sustainability of the described processes. Topics such as synthetic methodology, catalysis, and development of new solvent systems or greener alternative reagents are addressed. The chemistry of vegetable oil derivatives, terpenes, lignin, carbohydrates, and sugar-based platform chemicals was selected to highlight the trends in the active field of a sustainable use of renewable resources.
机译:利用不同生物质资源的结构多样性,最近的工作针对可再生单体和聚合物的合成,以替代石油基资源或设计新型聚合物。不仅使用生物质,而且开发可持续的化学方法也是生产可持续材料的关键方面。这篇综述讨论了丰富的生物质资源的化学修饰和聚合反应的最新实例,并将重点明确放在了所描述过程的可持续性上。讨论了诸如合成方法,催化和开发新溶剂系统或更环保的替代试剂等主题。选择了植物油衍生物,萜烯,木质素,碳水化合物和糖基平台化学品的化学成分,以突出可持续利用可再生资源这一积极领域的趋势。

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