Development of Axially Chiral Cyclo-Biaryldiol Ligands with Adjustable Dihedral Angles

Zhang Pengxiang; Yu Jipan; Peng Fei; Wu Xudong; Jie Jiyang; Liu Can; Tian Hua; Yang Haijun; Fu Hua

首页> 外文期刊>Chemistry: A European journal >Development of Axially Chiral Cyclo-Biaryldiol Ligands with Adjustable Dihedral Angles

【24h】

Development of Axially Chiral Cyclo-Biaryldiol Ligands with Adjustable Dihedral Angles

机译：二面角可调的轴向手性环-联芳基二醇配体的开发

获取原文

获取原文并翻译 | 示例

掌桥外文数据库（机构版） >>

开具论文收录证明 >>

文献代查 >>

页面导航

摘要
著录项
相似文献
相关主题

摘要

A new type of axially chiral cyclo-[1,1-biphenyl]-2,2-diol (CYCNOL) ligands with adjustable dihedral angles have been developed by varying the bridge chain length. Eight-, nine- and ten-membered cyclo-ligands were prepared and evaluated by using two representative examples: enantioselective additions of diethylzinc to aldehydes and organometallic reagents to enones. The results revealed that the fine regulation of dihedral angles through variation of the bridge chain length was effective in the asymmetric synthesis.

机译：通过改变桥链长度，开发了一种新型的具有可调节二面角的轴向手性环-[1,1-联苯] -2,2-二醇（CYCNOL）配体。通过两个代表性的例子，制备并评估了八元，九元和十元环配体：将二乙基锌对醛选择性对映选择性添加，将有机金属试剂对烯酮选择性添加。结果表明，通过改变桥链长度对二面角的精细调节在不对称合成中是有效的。

著录项

来源
《Chemistry: A European journal》 |2016年第48期|共8页
作者
Zhang Pengxiang; Yu Jipan; Peng Fei; Wu Xudong; Jie Jiyang; Liu Can; Tian Hua; Yang Haijun; Fu Hua;
展开▼
作者单位

展开▼
收录信息
原文格式 PDF
正文语种 eng
中图分类
关键词
asymmetric catalysis; asymmetric synthesis; enantioselectivity; ligand design; ligand effects;

机译：不对称催化;不对称合成;对映选择性;配体设计;配体效应;

相似文献

外文文献
中文文献
专利

1. Development of Axially Chiral Cyclo-Biaryldiol Ligands with Adjustable Dihedral Angles [J] . Zhang Pengxiang, Yu Jipan, Peng Fei, Chemistry: A European journal . 2016,第48期

机译：二面角可调的轴向手性环-联芳基二醇配体的开发
2. Chiral extraction of amino acid and mandelic acid enantiomers using chiral diphosphine ligands with tunable dihedral angles [J] . Liu Xiong, Ma Yu, Liu Qi, Separation and Purification Technology . 2019,第期

机译：用可调谐二偏角角度使用手性二膦配体的氨基酸和颌骨酸对映体的手性提取
3. Models of the membrane-bound cytochromes: Mossbauer spectra of crystalline low-spin ferriheme complexes having axial ligand plane dihedral angles ranging from 0 degrees to 90 degrees [J] . Teschner T, Yatsunyk L, Schunemann V, Journal of the American Chemical Society . 2006,第4期

机译：膜结合细胞色素的模型：轴向配体平面二面角范围为0度至90度的结晶低自旋亚铁血红素复合物的Mossbauer光谱
4. Structural and Photophysical Properties of Eu(III) Coordination Polymer with an Axial Chiral Ligand [C] . Naovuki Koiso, Yuichi Kitagawa, Takayuki Nakanishi Rare Earth Research Conference . 2019

机译：欧盟（III）配位与轴向手性配体的结构和光物理性质
5. Development of new chiral chelating ferrocenyl ligands for transition metal catalyzed asymmetric carbon -carbon bond formations: A modular approach for ligand design and synthesis [D] . Cheung, Hong Yee 2008

机译：用于过渡金属催化的不对称碳-碳键形成的新手性螯合二茂铁基配体的开发：配体设计和合成的模块化方法
6. Models of the Membrane-Bound Cytochromes: Mössbauer Spectra of Crystalline Low-Spin Ferriheme Complexes Having Axial Ligand Plane Dihedral Angles Ranging from 0° to 90° [O] . Thomas Teschner, Liliya Yatsunyk, Volker Schünemann, -1

机译：膜结合细胞色素的模型：具有轴向配体平面二面角在0°至90°范围内的结晶性低自旋亚铁血红素复合物的Mössbauer光谱
7. Models of the Membrane-Bound Cytochromes: Mössbauer Spectra of Crystalline Low-Spin Ferriheme Complexes Having Axial Ligand Plane Dihedral Angles Ranging from 0° to 90° [O] . Thomas Teschner, Liliya Yatsunyk, Volker Schünemann, 2006

机译：膜结合细胞学的模型：晶体低旋转Ferriheme复合物的Mössbauer光谱，具有轴向配体平面二面角范围为0°至90°

Development of Axially Chiral Cyclo-Biaryldiol Ligands with Adjustable Dihedral Angles

摘要

著录项

相似文献

相关主题

期刊订阅