Incarceration of Higher-Order Fullerenes within Cyclotriveratrylene-Based Hemicarcerands Allows Selective Isolation of C-76, C-78, and C-84 from a Commercial Fullerene Mixture

Liu Kuang-Shun; Li Ming-Jhe; Lai Chien-Chen; Chiu Sheng-Hsien

首页> 外文期刊>Chemistry: A European journal >Incarceration of Higher-Order Fullerenes within Cyclotriveratrylene-Based Hemicarcerands Allows Selective Isolation of C-76, C-78, and C-84 from a Commercial Fullerene Mixture

【24h】

Incarceration of Higher-Order Fullerenes within Cyclotriveratrylene-Based Hemicarcerands Allows Selective Isolation of C-76, C-78, and C-84 from a Commercial Fullerene Mixture

机译：在基于环三茂铁的半陶瓷中嵌入更高阶的富勒烯可以从商业富勒烯混合物中选择性分离C-76，C-78和C-84

获取原文

获取原文并翻译 | 示例

掌桥外文数据库（机构版） >>

开具论文收录证明 >>

文献代查 >>

页面导航

摘要
著录项
相似文献
相关主题

摘要

Size-complementary cyclotriveratrylene (CTV)-based hosts can incarcerate C-76, C-78, and C-84, thus allowing the selective isolation of these higher-order fullerenes from a commercially available mixture of fullerenes. The hemicarceplexes, formed after the encapsulation of the size-complementary fullerenes within the hosts, are isolated by column chromatography and released at elevated temperature, thereby leading to the isolation of C-76/C-78 and C-84 in good purities (up to 95 and 88%, respectively).

机译：基于尺寸互补的环三碳杂戊二烯（CTV）的主体可以嵌入C-76，C-78和C-84，因此可以从市售的富勒烯混合物中选择性分离这些高级富勒烯。将大小互补的富勒烯包封在宿主体内后形成的半链状复合物，通过柱色谱法分离并在高温下释放，从而以良好的纯度分离出C-76 / C-78和C-84（向上分别为95％和88％）。

著录项

来源
《Chemistry: A European journal》 |2016年第48期|共9页
作者
Liu Kuang-Shun; Li Ming-Jhe; Lai Chien-Chen; Chiu Sheng-Hsien;
展开▼
作者单位

展开▼
收录信息
原文格式 PDF
正文语种 eng
中图分类
关键词
cyclotriveratrylenes; cage compounds; fullerenes; hemicarceplexes; host-guest systems;

机译：环三亚芳基萘;笼型化合物;富勒烯;半水合物;宿主-客体系统;

相似文献

外文文献
中文文献
专利

1. Incarceration of Higher-Order Fullerenes within Cyclotriveratrylene-Based Hemicarcerands Allows Selective Isolation of C-76, C-78, and C-84 from a Commercial Fullerene Mixture [J] . Liu Kuang-Shun, Li Ming-Jhe, Lai Chien-Chen, Chemistry: A European journal . 2016,第48期

机译：在基于环三茂铁的半陶瓷中嵌入更高阶的富勒烯可以从商业富勒烯混合物中选择性分离C-76，C-78和C-84
2. SINGLE-PHOTON IONIZATION OF HIGHER FULLERENES C-76, C-78 AND C-84 - DETERMINATION OF IONIZATION POTENTIALS [J] . Steger H., Hielscher A., Kamke W., Chemical Physics Letters . 1995,第4a6期

机译：高级富勒烯C-76，C-78和C-84的单光子电离-电离电位的测定
3. REVERSIBLE FULLERENE ELECTROCHEMISTRY - CORRELATION WITH THE HOMO-LUMO ENERGY DIFFERENCE FOR C-60, C-70, C-76, C-78, AND C-84 [J] . Yang YF., Echegoyen L., Chibante LPF., Journal of the American Chemical Society . 1995,第29期

机译：可逆富勒烯电化学-与C-60，C-70，C-76，C-78和C-84的同质光能差异相关
4. Recovery and Isolation of Higher Fullerenes and Metallofullerenes Via Selective Chemical Release from Waste Materials [C] . Katelyn R. Tepper, Steven Stevenson Meeting of the Electrochemical Society;International Meeting on Chemical Sensors . 2020

机译：通过从废料中选择性化学释放的选择性化学释放回收和分离更高的富勒烯和金属嘧啶
5. Separation and Selective Formation of Fullerene Adducts within an MII8L6 Cage [O] . Wolfgang Brenner, Tanya K. Ronson, Jonathan R. Nitschke 2016

机译：MII8L6笼内的富勒烯加合物的分离和选择性形成

Incarceration of Higher-Order Fullerenes within Cyclotriveratrylene-Based Hemicarcerands Allows Selective Isolation of C-76, C-78, and C-84 from a Commercial Fullerene Mixture

摘要

著录项

相似文献

相关主题

期刊订阅