Design of 2D Porous Coordination Polymers Based on Metallacrown Units

Atzeri Corrado; Marchio Luciano; Chow Chun Y.; Kampf Jeff W.; Pecoraro Vincent L.; Tegoni Matteo

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Design of 2D Porous Coordination Polymers Based on Metallacrown Units

机译：基于金属缺陷单元的二维多孔配位聚合物的设计

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A 12-metallacrown-4 (MC) complex was designed and employed as the building block in the synthesis of coordination polymers, one of which is the first permanently porous MC architecture. The connection of the four-fold symmetric MC subunits by Cu-II nodes led to the formation of 2D layers of metallacrowns. Channels are present in the crystalline architecture, which exhibits permanent porosity manifested in N-2 and CO2 uptake capacity.

机译：设计了一种12-metallacrown-4（MC）配合物，并将其用作配位聚合物合成的基础，其中第一个是永久性多孔MC结构。 Cu-II节点将四重对称的MC亚基连接起来，导致形成了2D的金属层。通道存在于晶体结构中，表现出以N-2和CO2吸收能力表现出的永久孔隙率。

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《Chemistry: A European journal》 |2016年第19期|共5页
作者
Atzeri Corrado; Marchio Luciano; Chow Chun Y.; Kampf Jeff W.; Pecoraro Vincent L.; Tegoni Matteo;
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正文语种 eng
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关键词
coordination polymers; gas adsorption; hydroxamic acids; metallacrowns; porosity;

机译：配位聚合物;气体吸附;异羟肟酸;金属漆;孔隙度;

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1. Design of 2D Porous Coordination Polymers Based on Metallacrown Units [J] . Atzeri Corrado, Marchio Luciano, Chow Chun Y., Chemistry: A European journal . 2016,第19期

机译：基于金属缺陷单元的二维多孔配位聚合物的设计
2. Porous 2D coordination polymeric formate built up by Mn(II) linking of Fe3O units: influence of guest molecules on magnetic properties [J] . Lytvynenko AS, Kolotilov SV, Cador O, Dalton transactions: An international journal of inorganic chemistry . 2009,第18期

机译：由Fe3O单元的Mn（II）连接建立的多孔二维配位聚合物甲酸酯：客体分子对磁性的影响
3. Structure, magnetic, and electrochemical properties of complexes of 3d-metals as redox-active units for assembling coordination polymers and porous coordination polymer on their basis [J] . Lytvynenko A. S., Mishura A. M., Titov V. E., Russian Chemical Bulletin . 2015,第2期

机译：用作配位聚合物和多孔配位聚合物的氧化还原活性单元的3d金属配合物的结构，磁性和电化学性质
4. The Design of 2DOF Enhance Coordination Unit of Ammunition [C] . Guobao Ding, He Cui, Xiuwen Hu International Conference on Information Engineering for Mechanics and Materials . 2016

机译：2DOF增强弹药协调单位的设计
5. Designs of Nitrogen Donating Ligands in Metal Organic Polymeric Anion Exchangers and Iron-Based Coordination Polymers [D] . Soe, Eaindar 2018

机译：金属有机高分子阴离子交换剂和铁基配位聚合物中供氮配体的设计
6. Correction: Rocco D.; et al. Competition in Coordination Assemblies: 1D-Coordination Polymer or 2D-Nets Based on Co(NCS)2 and 4′-(4-methoxy)-32′:6′3″-terpyridine. Polymers 2019 11 1224; doi:10.3390/polym11071224 [O] . Dalila Rocco, Alessandro Prescimone, Y. Maximilian Klein, 2019

机译：更正：RoccoD .；等。配位组装的竞争：基于Co（NCS）2和4-（4-甲氧基）-32：63-叔吡啶的1D配位聚合物或2D-网。聚合物2019111224; doi：10.3390 / polym11071224
7. Design of 2D Porous Coordination Polymers Based on Metallacrown Units [O] . Atzeri, Corrado, Marchiò, Luciano, Chow, Chun Y., 2016

机译：基于metallacrown单元的二维多孔配位聚合物的设计

Design of 2D Porous Coordination Polymers Based on Metallacrown Units

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