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Cage-to-Cage Cascade Transformations

机译:笼到笼级联转换

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摘要

A series of Pd2L4-type binuclear self-assembled coordination cages (1-4), where L stands for a nonchelating bidentate ligand, were prepared. The strategies adopted for the synthesis of the cages were: combination of Pd-II with 1)a selected ligand or 2)subcomponents of the ligand. Highly efficient cage-to-cage transformation reactions are demonstrated by suitable covalent modification (from 1 to 2 or 3 or 4) or ligand-exchange reactions (from 1 to 2 or 3 or 4; from 2 to 3 or 4). Thus, new cascade transformations (from 1 to 2 to 3; from 1 to 2 to 4) are achieved beautifully.
机译:制备了一系列Pd2L4型双核自组装配位笼(1-4),其中L代表非螯合双齿配体。笼子合成所采用的策略是:Pd-II与1)选定的配体或2)配体的亚组分结合。通过适当的共价修饰(从1到2或3或4)或配体交换反应(从1到2或3或4;从2到3或4)证明了高效的笼到笼转化反应。因此,可以很好地实现新的级联转换(从1到2到3;从1到2到4)。

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