Induced Circular Dichroism in Phosphine Gold(I) Aryl Acetylide Urea Complexes through Hydrogen-Bonded Chiral Co-Assemblies

Dubarle-Offner Julien; Moussa Jamal; Amouri Hani; Jouvelet Benjamin; Bouteiller Laurent; Raynal Matthieu

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Induced Circular Dichroism in Phosphine Gold(I) Aryl Acetylide Urea Complexes through Hydrogen-Bonded Chiral Co-Assemblies

机译：通过氢键合手性共组装体在磷化氢金（I）芳基乙酰化脲复合物中诱导圆二色性

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Phosphine gold(I) aryl acetylide complexes equipped with a central bis(urea) moiety form 1D hydrogen-bonded polymeric assemblies in solution that do not display any optical activity. Chiral co-assemblies are formed by simple addition of an enantiopure (metal-free) complementary monomer. Although exhibiting an intrinsically achiral linear geometry, the gold(I) aryl acetylide fragment is located in the chiral environment displayed by the hydrogen-bonded co-assemblies, as demonstrated by induced circular dichroism (ICD).

机译：配备有中心双（脲）部分的膦金（I）芳基乙炔化物络合物在溶液中形成一维氢键键合的聚合物组件，该组件不显示任何光学活性。通过简单添加对映纯（不含金属）的互补单体可形成手性共装配体。尽管表现出本质上非手性的线性几何形状，但是金（I）芳基乙炔基金片段位于氢键合共组装体所显示的手性环境中，如诱导圆二色性（ICD）所示。

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《Chemistry: A European journal》 |2016年第12期|共6页
作者
Dubarle-Offner Julien; Moussa Jamal; Amouri Hani; Jouvelet Benjamin; Bouteiller Laurent; Raynal Matthieu;
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正文语种 eng
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supramolecular chirality; gold complexes; induced circular dichroism; sergeants and soldiers; supramolecular polymers;

机译：超分子手性;金配合物;诱导的圆二色性;军士和士兵;超分子聚合物;

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1. Induced Circular Dichroism in Phosphine Gold(I) Aryl Acetylide Urea Complexes through Hydrogen-Bonded Chiral Co-Assemblies [J] . Dubarle-Offner Julien, Moussa Jamal, Amouri Hani, Chemistry: A European journal . 2016,第12期

机译：通过氢键合手性共组装体在磷化氢金（I）芳基乙酰化脲复合物中诱导圆二色性
2. Giant plasmonically induced circular conversion dichroism in an anisotropic golden slit grating filled by a chiral medium [J] . Ming Yong, Sun Song, Zhang Yongliang, Physical review, B . 2019,第12期

机译：巨型量相诱导的循环转换二色性在由手性介质填充的各向异性金黄狭缝光栅中
3. Chirality transfer in nematic liquid crystals doped with (S)-naproxen-functionalized gold nanoclusters:an induced circular dichroism study [J] . Hao Qi, Joe ONeil, Torsten Hegmann Journal of Materials Chemistry: An Interdisciplinary Journal dealing with Synthesis, Structures, Properties and Applications of Materials, Particulary Those Associated with Advanced Technology . 2008,第4期

机译：（S）-萘普生官能化的金纳米团簇掺杂向列液晶的手性转移：诱导圆二色性研究
4. Simulation of circular dichroism enhancement in gold nanocuboids array lled by chiral medium for optical frequency range [C] . Egor A. Gurvitz, Alexander S. Shalin International Conference on Days on Diffraction . 2017

机译：手性介质在光频率范围内增强金纳米立方体阵列的圆二色性的模拟
5. Mechanism of the palladium-catalyzed amination of aryl halides: Kinetic studies of the oxidative addition of aryl halides and sulfonates to phosphine complexes of Pd(0) and of the catalytic reaction of amines with aryl halides and base. [D] . Alcazar-Roman, Luis Manuel. 2001

机译：钯催化芳基卤化物胺化的机理：动力学研究氧化芳基卤化物和磺酸盐到Pd（0）的膦配合物中，以及胺与芳基卤化物和碱的催化反应。
6. Chirality transfer from gold nanocluster to adsorbate evidenced by vibrational circular dichroism [O] . Igor Dolamic, Birte Varnholt, Thomas Bürgi -1

机译：手性从金纳米团簇向吸附物的转移通过振动圆二色性证明
7. Induced Circular Dichroism in Phosphine Gold(I) Aryl Acetylide Urea Complexes through Hydrogen-Bonded Chiral Co-Assemblies [O] . Dubarle-Offner, Julien, Moussa, Jamal, Amouri, Hani, 2016

机译：通过氢键合手性共组装体在磷化氢金（I）芳基乙酰丙酮尿素配合物中诱导圆二色性
8. Circular Dichroism Studies of Metal Complexes of Chiral Drug (Cephalexin) [R] . Riaz, A. 1992

机译：手性药物金属配合物（头孢氨苄）的圆二色谱研究

Induced Circular Dichroism in Phosphine Gold(I) Aryl Acetylide Urea Complexes through Hydrogen-Bonded Chiral Co-Assemblies

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