Nucleophilic Additions to Coordinated 1,10-Phenanthroline: Intramolecular, Intermolecular, Reversible, and Irreversible

Arevalo Rebeca; Isabel Menendez M.; Lopez Ramon; Merino Isabel; Riera Lucia; Perez Julio

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Nucleophilic Additions to Coordinated 1,10-Phenanthroline: Intramolecular, Intermolecular, Reversible, and Irreversible

机译：1,10-邻菲咯啉的亲核加成：分子内，分子间，可逆和不可逆

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KN(SiMe3)(2) reacts with [Re(CO)(3)(phen)(PMe3)]OTf via reversible addition to the phen ligand and irreversible deprotonation of the PMe3 ligand followed by intramolecular attack to phen by the deprotonated phosphane, whereas MeLi irreversibly adds to phen. The addition of MeLi has been shown to be intermolecular, unlike previously known nucleophilic additions to pyridines.

机译：KN（SiMe3）（2）与[Re（CO）（3）（phen）（PMe3）] OTf通过可逆地添加到phen配体和PMe3配体不可逆地去质子化，然后通过去质子化的膦烷对phen进行分子内攻击，而MeLi不可逆地增加了phen。已证明MeLi的添加是分子间的，与先前已知的向吡啶的亲核添加不同。

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《Chemistry: A European journal》 |2016年第50期|共4页
作者
Arevalo Rebeca; Isabel Menendez M.; Lopez Ramon; Merino Isabel; Riera Lucia; Perez Julio;
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N ligands; nucleophilic addition; phenanthroline complexes; pyridine dearomatization; rhenium carbonyls;

机译：N配体;亲核加成;菲咯啉配合物;吡啶脱芳香化;羰基hen;

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1. Nucleophilic Additions to Coordinated 1,10-Phenanthroline: Intramolecular, Intermolecular, Reversible, and Irreversible [J] . Arevalo Rebeca, Isabel Menendez M., Lopez Ramon, Chemistry: A European journal . 2016,第50期

机译：1,10-邻菲咯啉的亲核加成：分子内，分子间，可逆和不可逆
2. UV Photolysis of a Re(I) Macromolecule, [(4-vinylpyridine)_2(4-vinylpyridineRe(CO)_3(1,10-phenanthroline)~+]_(200): Addition of C-centered Radicals to Coordinated CO [J] . E. Wolcan, G. Ferraudi, M. R. Feliz, Supramolecular chemistry . 2003,第2期

机译：Re（I）高分子[（4-乙烯基吡啶）_2（4-乙烯基吡啶Re（CO）_3（1,10-菲咯啉）〜+] _（200）的紫外光解：将以C为中心的自由基加到配位的CO
3. Addition of N-Acyliminium Ion Pools to Alkenes Having a Nucleophilic Moiety: Integration of Intermolecular and Intramolecular Reactions [J] . Yosuke Ashikari, Yohei Kiuchi, Tomoya Takeuchi Chemistry Letters . 2014,第2期

机译：N-酰基亚胺离子池添加到具有亲核部分的烯烃：分子间和分子内反应的整合。
4. Silver(I)-Catalyzed Intramolecular and Intermolecular Addition Reactions [C] . Sonoko Matsui, Risa Kato, Kentaro Hamashima Symposium on Organometallic Chemistry . 2007

机译：银（i） - 催化分子内和分子间添加反应
5. The Luminescent Properties of Europium Thenoyltrifluoroacetone Complexes with 2-Phenyl-1h-Imidazo[4,5-f][1,10]Phenanthroline Based Ligands [D] . Venturo, Paul Jacob. 2020

机译：铕的发光特性罗霉氟丙酮配合物用2-苯基-1H-咪唑络合物[4,5-F] [1,10]菲芳啉基配体
6. 1,10-Phenanthrolinium 4-chloro-2-hydroxybenzoate–1,10-phenanthroline–4-chloro-2-hydroxybenzoic acid (1/1/1) [O] . Hong Shen, Jing-Jing Nie, Duan-Jun Xu 2015

机译：1,10-菲咯啉4-氯-2-羟基苯甲酸–1,10-菲咯啉–4-氯-2-羟基苯甲酸（1/1/1）
7. Nucleophilic additions to coordinated 1,10-phenanthroline: intramolecular, intermolecular, reversible, and irreversible [O] . Arévalo, Rebeca, Menéndez, M. Isabel, López, Ramón, 2016

机译：1,10-菲咯啉的亲核添加物：分子内，分子间，可逆和不可逆

Nucleophilic Additions to Coordinated 1,10-Phenanthroline: Intramolecular, Intermolecular, Reversible, and Irreversible

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