• 主题
高级搜索  >
历史搜索 清空历史
首页> 外文期刊>Chemistry: A European journal >Resonance-Assisted Hydrogen Bonding as a Driving Force in Synthesis and a Synthon in the Design of Materials
【24h】

Resonance-Assisted Hydrogen Bonding as a Driving Force in Synthesis and a Synthon in the Design of Materials

机译：共振辅助氢键作为合成中的驱动力和材料设计中的合成子

获取原文
获取原文并翻译 | 示例
           
页面导航
  • 摘要
  • 著录项
  • 相似文献
  • 相关主题

摘要

Resonance-assisted hydrogen bonding (RAHB), a concept introduced by Gilli and co-workers in 1989, concerns a kind of intramolecular H-bonding strengthened by a conjugated -system, usually in 6-, 8-, or 10-membered rings. This Review highlights the involvement of RAHB as a driving force in the synthesis of organic, coordination, and organometallic compounds, as a handy tool in the activation of covalent bonds, and in starting moieties for synthetic transformations. The unique roles of RAHB in molecular recognition and switches, E/Z isomeric resolution, racemization and epimerization of amino acids and chiral amino alcohols, solvatochromism, liquid-crystalline compounds, and in synthons for crystal engineering and polymer materials are also discussed. The Review can provide practical guidance for synthetic chemists that are interested in exploring and further developing RAHB-assisted synthesis and design of materials.
机译：共振辅助氢键（RAHB）是吉利（Gilli）及其同事于1989年提出的概念，它涉及一种通过共轭体系（通常在6、8或10元环上）增强的分子内氢键。这篇综述着重介绍了RAHB作为有机，配位和有机金属化合物合成的驱动力，是激活共价键和合成转化起始部分的便捷工具。还讨论了RAHB在分子识别和转换，E / Z异构体拆分，氨基酸和手性氨基醇的消旋化和差向异构化，溶剂化变色，液晶化合物以及在用于晶体工程和聚合物材料的合成子中的独特作用。该综述可以为有兴趣探索和进一步开发RAHB辅助材料的合成和设计的合成化学家提供实用指南。

著录项

相似文献

  • 外文文献
  • 中文文献
  • 专利
获取原文

客服邮箱：kefu@zhangqiaokeyan.com

京公网安备：11010802029741号 ICP备案号：京ICP备15016152号-6 六维联合信息科技 (北京) 有限公司©版权所有

  • 客服微信

  • 服务号