A Modular Class of Fluorescent Difluoroboranes: Synthesis, Structure, Optical Properties, Theoretical Calculations and Applications for Biological Imaging

Bachollet Sylvestre P. J. T.; Volz Daniel; Fiser Bela; Muench Stephan; Roenicke Franziska; Carrillo Jokin; Adams Harry; Schepers Ute; Gomez-Bengoa Enrique; Braese Stefan; Harrity Joseph P. A.

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A Modular Class of Fluorescent Difluoroboranes: Synthesis, Structure, Optical Properties, Theoretical Calculations and Applications for Biological Imaging

机译：荧光二氟硼烷的模块类：合成，结构，光学性质，理论计算和生物成像的应用。

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Ten borylated bipyridines (BOBIPYs) have been synthesized and selected structural modifications have been made that allow useful structure-optical property relationships to be gathered. These systems have been further investigated using DFT calculations and spectroscopic measurements, showing blue to green fluorescence with quantum yields up to 41%. They allow full mapping of the structure to determine where selected functionalities can be implemented, to tune the optical properties or to incorporate linking groups. The best derivative was thus functionalised with an alkyne linker, which would enable further applications through click chemistry and in this optic, the stability of the fluorophores has been evaluated.

机译：已经合成了十个硼化的联吡啶（BOBIPY），并进行了选定的结构修饰，从而可以收集有用的结构-光学性质关系。使用DFT计算和光谱测量对这些系统进行了进一步研究，显示出蓝色至绿色荧光，量子产率高达41％。它们允许对结构进行完整映射，以确定可以在何处实现所选功能，调整光学特性或合并连接基团。因此，最好的衍生物是用炔烃连接基官能化的，这可以通过点击化学实现进一步的应用，并且在这种光学器件中，已经评估了荧光团的稳定性。

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《Chemistry: A European journal》 |2016年第35期|共9页
作者
Bachollet Sylvestre P. J. T.; Volz Daniel; Fiser Bela; Muench Stephan; Roenicke Franziska; Carrillo Jokin; Adams Harry; Schepers Ute; Gomez-Bengoa Enrique; Braese Stefan; Harrity Joseph P. A.;
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正文语种 eng
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borylated bipyridines; cell imaging; density functional calculations; fluorophore; photophysics;

机译：硼化联吡啶;细胞成像;密度泛函计算;荧光团;光物理;

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1. A Modular Class of Fluorescent Difluoroboranes: Synthesis, Structure, Optical Properties, Theoretical Calculations and Applications for Biological Imaging [J] . Bachollet Sylvestre P. J. T., Volz Daniel, Fiser Bela, Chemistry: A European journal . 2016,第35期

机译：荧光二氟硼烷的模块类：合成，结构，光学性质，理论计算和生物成像的应用。
2. A series of novel NIR fluorescent dyes: Synthesis, theoretical calculations and fluorescence imaging applications in living cells [J] . Zhang Ming, Zheng Shu-ting, Liu Xiao-jing, Dyes and Pigments . 2016,第Null期

机译：一系列新型NIR荧光染料：活细胞的合成，理论计算和荧光成像应用
3. A rhodamine-based fluorescent probe for Hg2+: synthesis, theoretical calculations and bio-imaging applications [J] . Zhang Ming, Liu Xiaojing, Bao Yi, Tetrahedron . 2016,第2期

机译：基于罗丹明的Hg2 +荧光探针：合成，理论计算和生物成像应用
4. A new Class of Conjugated Strigolactone Analogues with Fluorescent Properties: Synthesis and Biological Activity [C] . Paola Bonfante, Yoram Kapulnik, Paolo Larini European Symposium on Organic Chemistry . 2009

机译：具有荧光特性的新一类共轭杂交类似物：合成和生物活性
5. Nano-engineered structure for a fluorescent nitric oxide sensor in optical imaging application. [D] . Zhang, Guodong. 2009

机译：用于光学成像应用的一氧化氮荧光传感器的纳米工程结构。
6. A novel approach to study the structure-property relationships and applications in living systems of modular Cu2+ fluorescent probes [O] . Mengyao She, Zheng Yang, Likai Hao, -1

机译：研究模块化Cu2 +荧光探针在生命系统中的结构-特性关系及其应用的新方法
7. A Modular Class of Fluorescent Difluoroboranes: Synthesis, Structure, Optical Properties, Theoretical Calculations and Applications for Biological Imaging. [O] . Bachollet S.P., Volz D., Fiser B., 2016

机译：模块化荧光二氟硼烷类：生物成像的合成，结构，光学性质，理论计算和应用。

A Modular Class of Fluorescent Difluoroboranes: Synthesis, Structure, Optical Properties, Theoretical Calculations and Applications for Biological Imaging

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