Synthesis of Cyclic Carbonates Catalysed by Chromium and Aluminium Salphen Complexes

Castro-Osma Jose A.; North Michael; Wu Xiao

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Synthesis of Cyclic Carbonates Catalysed by Chromium and Aluminium Salphen Complexes

机译：铬铝螯合物配合物催化合成环状碳酸酯

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Chromium and aluminium salphen complexes have been found to display remarkable catalytic activity in the synthesis of cyclic carbonates from a range of epoxides and carbon dioxide. The Al(salphen) complex is more reactive towards terminal epoxides at ambient temperature and pressure, whereas the Cr(salphen) complex exhibits higher catalytic activity towards more challenging internal epoxides at elevated temperature and pressure.

机译：已发现铬和铝的马来酮络合物在由多种环氧化物和二氧化碳合成环状碳酸酯时显示出显着的催化活性。 Al（salphen）络合物在环境温度和压力下对末端环氧化物更具反应性，而Cr（salphen）络合物在升高的温度和压力下对更具挑战性的内部环氧化物表现出更高的催化活性。

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《Chemistry: A European journal》 |2016年第6期|共8页
作者
Castro-Osma Jose A.; North Michael; Wu Xiao;
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正文语种 eng
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关键词
aluminium; chromium; cyclic carbonates; epoxides; homogeneous catalysis; salphen ligands;

机译：铝;铬;环状碳酸酯;环氧化物;均相催化;塞芬配体;

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专利

1. Synthesis of Cyclic Carbonates Catalysed by Chromium and Aluminium Salphen Complexes [J] . Castro-Osma Jose A., North Michael, Wu Xiao Chemistry: A European journal . 2016,第6期

机译：铬铝螯合物配合物催化合成环状碳酸酯
2. Unprecedented Carbonato Intermediates in Cyclic Carbonate Synthesis Catalysed by Bimetallic Aluminium(Salen) Complexes [J] . Castro-Osma Jose A., North Michael, Offermans Willem K., ChemSusChem . 2016,第8期

机译：前所未有的Carbonato中间体中的碳酸盐合成，由双金属铝（Salen）复合物催化
3. Synthesis of Cyclic Carbonates Catalysed by Aluminium Heteroscorpionate Complexes [J] . Martinez Javier, Castro-Osma Jose A., Earlam Amy, Chemistry: A European journal . 2015,第27期

机译：杂铝酸铝配合物催化合成环状碳酸酯
4. Polymerization Catalyses of Chromium Complexes Having N-donor Ligands [C] . Kenii Sogo, Yuushou Nakayama, Hajime Yasuda Symposium on Organometallic Chemistry . 2003

机译：具有N-供体配体的铬配合物的聚合催化剂
5. The synthesis and characterization of a new family of cyclic carbonate monomers, poly(ester-carbonates), and tin-based macroinitiators. [D] . Mullen, Brian Daniel. 2003

机译：新型的环状碳酸酯单体，聚（碳酸酯）和锡基大分子引发剂的合成与表征。
6. Robust bifunctional aluminium–salen catalysts for the preparation of cyclic carbonates from carbon dioxide and epoxides [O] . Yuri A Rulev, Zalina Gugkaeva, Victor I Maleev, 2015

机译：耐用的双功能铝-salen催化剂用于从二氧化碳和环氧化物制备环状碳酸酯
7. Isocyanurate Formation During Oxazolidinone Synthesis from Epoxides and Isocyanates Catalysed by a Chromium(Salphen) Complex [O] . Wu, Xiao, Mason, Jess, North, Michael 2017

机译：由铬（salphen）络合物催化的环氧化物和异氰酸酯合成恶唑烷酮时形成异氰脲酸酯

Synthesis of Cyclic Carbonates Catalysed by Chromium and Aluminium Salphen Complexes

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