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Small Cation-Based High-Performance Energetic Nitraminofurazanates

机译:基于小型阳离子的高性能富拉氮呋喃酸盐

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摘要

Large nitramino-substituted furazan anions were combined with small cations (hydroxylammonium, hydrazinium, and ammonium) to form a series of energetic salts that was fully characterized. The structures of several of the compounds (1a, 2a, 3a, and 4a) were further confirmed by single-crystal X-ray diffraction. Based on their physiochemical properties, such as density, thermal stability, and sensitivity, together with the calculated detonation properties, it was found that they exhibit good detonation performance and have potential application as high-energy-density materials.
机译:大的硝基氨基取代的呋喃山阴离子与小阳离子(羟基铵,肼和铵)结合形成一系列已充分表征的高能盐。通过单晶X射线衍射进一步证实了几种化合物(1a,2a,3a和4a)的结构。基于它们的物理化学性质,例如密度,热稳定性和敏感性,以及计算出的爆轰性质,发现它们表现出良好的爆轰性能并且作为高能量密度材料具有潜在的应用。

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