Probing the Limits of Selectivity in a Recognition-Mediated Reaction Network Embedded within a Dynamic Covalent Library

Kosikova Tamara; Mackenzie Harry; Philp Douglas

首页> 外文期刊>Chemistry: A European journal >Probing the Limits of Selectivity in a Recognition-Mediated Reaction Network Embedded within a Dynamic Covalent Library

【24h】

Probing the Limits of Selectivity in a Recognition-Mediated Reaction Network Embedded within a Dynamic Covalent Library

机译：探索嵌入在动态共价库中的识别介导的反应网络中的选择性极限

获取原文

获取原文并翻译 | 示例

掌桥外文数据库（机构版） >>

开具论文收录证明 >>

文献代查 >>

页面导航

摘要
著录项
相似文献
相关主题

摘要

Two recognition-mediated reaction processes operating through reactive binary complexes drive resolution of a 24-component dynamic covalent library, assembled from individual aldehydes and nucleophiles. The effectiveness of the library resolution and selective amplification of one recognition-enabled species over another is limited by the difference in the rates of the recognition-mediated reactive processes and the strength of the recognition processes employed in the dynamic system.

机译：通过反应性二元配合物进行的两个识别介导的反应过程可驱动由单个醛和亲核试剂组装而成的24组分动态共价库的拆分。文库解析和一个识别能力强的物种对另一物种的选择性扩增的有效性受到识别介导的反应过程速率和动态系统中识别过程强度的差异的限制。

著录项

来源
《Chemistry: A European journal》 |2016年第5期|共9页
作者
Kosikova Tamara; Mackenzie Harry; Philp Douglas;
展开▼
作者单位

展开▼
收录信息
原文格式 PDF
正文语种 eng
中图分类
关键词
combinatorial chemistry; cycloaddition reaction; kinetics; molecular recognition; NMR spectroscopy;

机译：组合化学环加成反应动力学分子识别核磁共振谱;

相似文献

外文文献
中文文献
专利

1. Probing the Limits of Selectivity in a Recognition-Mediated Reaction Network Embedded within a Dynamic Covalent Library [J] . Kosikova Tamara, Mackenzie Harry, Philp Douglas Chemistry: A European journal . 2016,第5期

机译：探索嵌入在动态共价库中的识别介导的反应网络中的选择性极限
2. Probing selectivity in recognition-mediated dynamic covalent processes [J] . Bennes RM, Philp D Organic letters . 2006,第17期

机译：在识别介导的动态共价过程中探索选择性
3. A recognition-mediated reaction drives amplification within a dynamic library [J] . Jan W. Sadownik, Douglas Philp Organic & biomolecular chemistry . 2015,第41期

机译：识别介导的反应驱动动态文库中的扩增
4. Synthetic Studies of Polymer Libraries Using Half-esters Obtainedby Practical Selective Monohydrolysis Reactions of SymmetricDiesters [C] . Satomi Niwayama, Jianjun Shi, Wataru Shoji 日本化学会春季年会 . 2020

机译：使用半酯的聚合物文库的合成研究获得了对称性的实际选择性单水解反应
5. Reparameterization of covalent bonding interactions in the AIREBO potential and application to reactions within carbon nanotubes. [D] . Piotrowski, Pamela Keating. 2005

机译：AIREBO电位中共价键相互作用的重新参数化及其在碳纳米管内的反应中的应用。
6. Competition-driven selection in covalent dynamic networks and implementation in organic reactional selectivity [O] . P. Kovaříček, A. C. Meister, K. Flídrová, 2018

机译：共价动态网络中竞争驱动的选择和有机反应选择性的实现
7. Probing the limits of selectivity in a recognition-mediated reaction network embedded within a dynamic covalent library [O] . Kosikova, Tamara, Mackenzie, Harry, Philp, Douglas 2016

机译：探索嵌入在动态共价库中的识别介导的反应网络中的选择性极限

Probing the Limits of Selectivity in a Recognition-Mediated Reaction Network Embedded within a Dynamic Covalent Library

摘要

著录项

相似文献

相关主题

期刊订阅