Combining the Advantages of Tetrazoles and 1,2,3-Triazoles: 4,5-Bis(tetrazol-5-yl)-1,2,3-triazole, 4,5-Bis(1-hydroxytetrazol-5-yl)-1,2,3-triazole, and their Energetic Derivatives

Dippold Alexander A.; Izsak Daniel; Klapoetke Thomas M.; Pflueger Carolin

首页> 外文期刊>Chemistry: A European journal >Combining the Advantages of Tetrazoles and 1,2,3-Triazoles: 4,5-Bis(tetrazol-5-yl)-1,2,3-triazole, 4,5-Bis(1-hydroxytetrazol-5-yl)-1,2,3-triazole, and their Energetic Derivatives

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Combining the Advantages of Tetrazoles and 1,2,3-Triazoles: 4,5-Bis(tetrazol-5-yl)-1,2,3-triazole, 4,5-Bis(1-hydroxytetrazol-5-yl)-1,2,3-triazole, and their Energetic Derivatives

机译：结合四唑和1,2,3-三唑的优点：4,5-双（四唑-5-基）-1,2,3-三唑，4,5-双（1-羟基四唑-5-基）- 1,2,3-三唑及其高能衍生物

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In the development of new energetic materials, the main challenge is the combination of high energy content with chemical and mechanical stability, two properties that are often contradictory. In this study, the syntheses and comprehensive characterizations of 4,5-bis(tetrazole-5-yl)-1,2,3-triazole and the novel 4,5-bis(1-hydroxytetrazole-5-yl)-1,2,3-triazole, as well as their energetic properties, are presented, combining the advantages of the more energetic tetrazole and the more stable 1,2,3-triazole rings. Nitrogen-rich salts of both compounds were synthesized to investigate their detonation performances and combustion behavior calculated by computer codes for potential application in erosion-reduced gun propellant mixtures due to their high nitrogen content. The structures of several of the compounds were studied by single-crystal X-ray diffraction and, especially in the case of 4,5-bis(tetrazol-5-yl)-1,2,3-triazole, revealed the site of deprotonation.

机译：在开发新的高能材料时，主要的挑战是高能量含量与化学和机械稳定性的结合，这两个性质通常是矛盾的。在这项研究中，合成并综合表征4,5-双（四唑-5-基）-1,2,3-三唑和新型4,5-双（1-羟基四唑-5-基）-1，介绍了2,3-三唑及其高能性能，结合了高能四唑和更稳定的1,2,3-三唑环的优点。合成了这两种化合物的富氮盐，以研究其爆轰性能和燃烧行为，这些爆裂性能和燃烧行为是由计算机代码计算的，由于其高氮含量，可潜在地应用于减蚀的火炮推进剂混合物中。通过单晶X射线衍射研究了几种化合物的结构，特别是在4,5-双（四唑-5-基）-1,2,3-三唑的情况下，揭示了去质子化的位置。

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《Chemistry: A European journal》 |2016年第5期|共11页
作者
Dippold Alexander A.; Izsak Daniel; Klapoetke Thomas M.; Pflueger Carolin;
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正文语种 eng
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cyclization; mechanical properties; N heterocycles; nitrogen oxides; structure elucidation;

机译：环化;力学性能;N杂环;氮氧化物;结构阐明;

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1. Combining the Advantages of Tetrazoles and 1,2,3-Triazoles: 4,5-Bis(tetrazol-5-yl)-1,2,3-triazole, 4,5-Bis(1-hydroxytetrazol-5-yl)-1,2,3-triazole, and their Energetic Derivatives [J] . Dippold Alexander A., Izsak Daniel, Klapoetke Thomas M., Chemistry: A European journal . 2016,第5期

机译：结合四唑和1,2,3-三唑的优点：4,5-双（四唑-5-基）-1,2,3-三唑，4,5-双（1-羟基四唑-5-基）- 1,2,3-三唑及其高能衍生物
2. Crystal and molecular structures of two triazole derivatives: 4-Cyclopropyl-4,5-dihydro-1H-1,2,3-triazole and Methyl 1-benzyl-1H-1,2,3- triazole-4-carboxylate [J] . Boechat N., De L. G. Ferreira M., Bastos M.M., Journal of chemical crystallography . 2010,第12期

机译：两种三唑衍生物的晶体和分子结构：4-环丙基-4,5-二氢-1H-1,2,3-三唑和1-苄基-1H-1,2,3-三唑-4-羧酸甲酯
3. Crystal and Molecular Structures of Two Triazole Derivatives: 4-Cyclopropyl-4,5-dihydro-1H-1,2,3-triazole and Methyl 1-benzyl-1H-1,2,3-triazole-4-carboxylate [J] . Journal of Chemical Crystallography . 2010,第12期

机译：两种三唑衍生物的晶体和分子结构：4-环丙基-4,5-二氢-1H-1,2,3-三唑和1-苄基-1H-1,2,3-三唑-4-羧酸甲酯
4. IDENTIFICATION AND INTERCONVERSION OF ISOMERIC 4,5-FUNCTIONALIZED 1,2,3THIADIAZOLES AND 1,2,3-TRIAZOLES IN CONDITIONS OF ELECTROSPRAY IONIZATION [C] . Marina Zimens, Dmitrii Mazur, Vasiliy Bakulev, International Mass Spectrometry Conference . 2018

机译：Ersomeric 4,5-官能化1,2,3-3亚唑和1,2,3-三唑在电喷雾电离条件下的鉴定和互联
5. New Thermally Stable Materials: I. Nucleophilic Azoles with Cyclic Perfluoroalkenes: II. Trifluoromethyl or Pentafluorosulfanyl Substituted Poly-1,2,3-triazoles; and III. Silver and Copper Derivatives of FOX-7 [D] . Garg, Sonali 2010

机译：新的热稳定材料：I.带有环状全氟烯烃的亲核腈：II。用三氟甲基或五氟硫烷基取代的聚1,2,3-三唑;和III。 FOX-7的银和铜衍生物
6. 4-{1-[4-(4-Bromophenyl)-1,3-thiazol-2-yl]-5-(4-fluorophenyl)-4,5-dihydro-1H-pyrazol-3-yl}-5-methyl-1-(4-methylphenyl)-1H-1,2,3-triazole [O] . Bakr F. Abdel-Wahab, Hanan A. Mohamed, Seik Weng Ng, 2015

机译：4- {1- [4-（4-溴苯基）-1,3-噻唑-2-基] -5-（4-氟苯基）-4,5-二氢-1H-吡唑-3-基} -5-甲基-1-（4-甲基苯基）-1H-1,2,3-三唑
7. Synthesis and crystal structure of bis(1H-benzo[d][1,2,3]triazole-κN2){2,2′-[N-(phenylphosphorylmethyl-κO)azanediyl]diacetato-κ3O,N,O′}cobalt(II)–1H-benzo[d][1,2,3]triazole (1/1) [O] . Chao-Jun Du, Xiao-Na Zhao 2017

机译：双（1H-苯并[d] [1,2,3]三唑-κN2）{2,2' - [N-（苯基磷酰基甲基-κO）氮杂二基]二乙酸酯-κ3O，N，O'}钴的合成和晶体结构（II）-1H-苯并[d] [1,2,3]三唑（1/1）
8. Solubility Report of 1-Methyl-3,5-Dinitro-1H-1,2,4-Triazole (MDNT) and 2-Methyl-4,5-Dinitro-2H-1,2,3-Triazole 1-Oxide (MDNTO) for Co-Crystallization Screen. [R] . Caflin, K. C., Sanchez, P. 2015

机译：1-甲基-3,5-二硝基-1H-1,2,4-三唑（mDNT）和2-甲基-4,5-二硝基-2H-1,2,3-三唑-1-氧化物（mDNTO）的溶解度报告）用于共结晶筛选。

Combining the Advantages of Tetrazoles and 1,2,3-Triazoles: 4,5-Bis(tetrazol-5-yl)-1,2,3-triazole, 4,5-Bis(1-hydroxytetrazol-5-yl)-1,2,3-triazole, and their Energetic Derivatives

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