The infrared spectrum of the benzoyl cation

Oomens J.; Bakker JM.; Sartakov BG.; Meijer G.; von Helden G.

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The infrared spectrum of the benzoyl cation

机译：苯甲酰基阳离子的红外光谱

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The vibrational spectrum of the gas phase benzoyl cation (C6H5CO+) in the 500-2500 cm(-1) range is presented. Vapor phase benzoic acid is photolyzed/photoionized using an ArF excimer laser and the resulting ionic fragments are stored in a quadrupole ion trap. The benzoyl cation is subsequently isolated and its infrared spectrum is recorded through multiple photon dissociation spectroscopy with a free electron laser. Density functional calculations predict a C-2v structure for the benzoyl cation, which is in good agreement with the observed spectrum. (C) 2002 Elsevier Science B.V. All rights reserved. [References: 23]

机译：给出了气相苯甲酰基阳离子（C6H5CO +）在500-2500 cm（-1）范围内的振动光谱。使用ArF受激准分子激光将气相苯甲酸进行光解/光电离，并将所得的离子碎片存储在四极离子阱中。随后分离出苯甲酰基阳离子，并利用自由电子激光通过多光子离解光谱法记录其红外光谱。密度泛函计算可预测苯甲酰基阳离子的C-2v结构，与观察到的光谱非常吻合。（C）2002 Elsevier Science B.V.保留所有权利。 [参考：23]

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《Chemical Physics Letters》 |2003年第6期|共5页
作者
Oomens J.; Bakker JM.; Sartakov BG.; Meijer G.; von Helden G.;
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正文语种 eng
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关键词
Ion-cyclotron resonance; Multiphoton dissociation; Molecular-ions; Photodissociation; Spectroscopy; Hydrocarbons; Fluorene;

机译：离子回旋共振;多光子离解;分子离子;光离解;光谱学;烃类;氟;

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1. The infrared spectrum of the benzoyl cation [J] . Oomens J., Bakker JM., Sartakov BG., Chemical Physics Letters . 2003,第5a6期

机译：苯甲酰基阳离子的红外光谱
2. Infrared spectra and quantum chemical characterization of weakly bound clusters of the benzoyl cation with Ar and H2O [J] . Alexander Patzer, Shamik Chakraborty, Otto Dopfer Physical chemistry chemical physics: PCCP . 2010,第48期

机译：带有Ar和H2O的苯甲酰基阳离子的弱键簇的红外光谱和量子化学表征
3. The study of the quantification of the concentration of benzoyl peroxide based on the terahertz spectrum [J] . X. A. Chen, Z. L. Zhou, L. Han, Materials Research Innovations . 2015,第Suppla10期

机译：基于太赫兹光谱的苯甲酰过氧化物浓度的定量研究
4. Infrared spectrum of the silicon hydride cation SiH7+ [C] . Yibin Cao, California Institute of Technology, Pasadena, Conference on laser techniques for state-selected and state-to-state chemistry . 1993

机译：氢化硅阳离子SiH7 +的红外光谱
5. Emerging microstructured fibers for linear and nonlinear optical applications in the mid-infrared and terahertz spectrum. [D] . Ung, Bora. 2012

机译：新兴的微结构光纤，用于中红外和太赫兹光谱中的线性和非线性光学应用。
6. A P25/(NH4)xWO3 hybrid photocatalyst with broad spectrum photocatalytic properties under UV visible and near-infrared irradiation [O] . Linfen Yang, Bin Liu, Tongyao Liu, -1

机译：在紫外线可见光和近红外光照射下具有广谱光催化性能的P25 /（NH4）xWO3杂化光催化剂
7. Studies on the Practical Application of Infrared Spectrum in the Field of Hygienic Chemical Research and Scientific Crime Investigation. I : Infrared Spectrum of Soil and Its Application for Discrimination. [O] . Saku Shinozaki, Kazuko Takagi, Ryoji Sawamura 1967

机译：红外光谱在卫生化学研究领域的实际应用研究及科学犯罪调查。我：土壤红外光谱及其鉴别申请。

The infrared spectrum of the benzoyl cation

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