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首页> 外文期刊>Chemical Physics Letters >On the nature of the smectic mesophase in 8CB+10CB binary mixtures. Evidences for a smectic A to nematic tricritical point
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On the nature of the smectic mesophase in 8CB+10CB binary mixtures. Evidences for a smectic A to nematic tricritical point

机译:关于近晶中间相在8CB + 10CB二元混合物中的性质。层列A到向列三临界点的证据

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摘要

The two-component system octylcyanobiphenyl(8CB) + decylcyanobiphenil(10CB) has been studied by means of Modulated Differential Scanning Calorimetry, optical microscopy and X-ray diffraction. Although the general trends of the phase diagram are similar to that proposed by Marynissen et al., additional evidences for the existence of TCP have been reported, the composition being about 0.2, which is slightly lower than that proposed in the aforementioned work. Additionally, the smectic mesophase of the 8CB + 10CB mixtures has been characterised through X-ray diffraction and optical measurements as smectic A for the whole composition range. Such a result is against the recent work of Oweimreen and Hwang. (C) 2003 Elsevier Science B.V. All rights reserved. [References: 29]
机译:通过调制差示扫描量热法,光学显微镜和X射线衍射研究了二组分系统辛基氰基联苯(8CB)+癸基氰基联苯(10CB)。尽管相图的总体趋势与Marynissen等人提出的相类似,但已报道了TCP存在的其他证据,其组成约为0.2,略低于上述工作中提出的组成。另外,已经通过X射线衍射和光学测量将8CB + 10CB混合物的近晶中间相表征为整个组成范围内的近晶A。这样的结果违背了奥维姆和黄某的最新工作。 (C)2003 Elsevier Science B.V.保留所有权利。 [参考:29]

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