Micellar structure of a sugar based bolaamphiphile in pure solution and destabilizing effects in mixtures of glycolipids

Garamus VM; Milkereit G; Gerber S; Vill V

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Micellar structure of a sugar based bolaamphiphile in pure solution and destabilizing effects in mixtures of glycolipids

机译：糖基双性亲脂纯溶液的胶束结构和糖脂混合物的去稳定作用

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We have synthesized a new type of bolaamphiphile with disaccharide headgroups at the polar terminus and an alkyl chain of 12 carbon atoms. The self organization properties of the pure compound in dilute aqueous solutions have been investigated using surface tension measurements critical micelle concentration (CMC) and small angle neutron scattering (aggregate structure). Additionally, we have used the bolaamphiphile as a dopant to solutions Of octyl-beta-D-glucoside. Addition of bolaamphiphile shifts the CMC to higher values compared to ideal mixing and decreases the size of micelles. (C) 2004 Elsevier B.V. All rights reserved.

机译：我们已经合成了一种新型的双亲两亲菌，其极性末端具有二糖头基，并且具有12个碳原子的烷基链。已使用表面张力测量临界胶束浓度（CMC）和小角度中子散射（聚集体结构）研究了纯化合物在稀水溶液中的自组织性质。另外，我们已经使用博来两亲试剂作为辛基-β-D-葡萄糖苷溶液的掺杂剂。相较于理想的混合，加入保兰两亲使CMC移至更高的值，并减小了胶束的大小。（C）2004 Elsevier B.V.保留所有权利。

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《Chemical Physics Letters》 |2004年第3期|共5页
作者
Garamus VM; Milkereit G; Gerber S; Vill V;
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正文语种 eng
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SMALL-ANGLE SCATTERING; GLYCOSYL DIACYLGLYCEROLS; NEUTRON-SCATTERING; COLLOIDS;

机译：小角度散射;糖基双糖醇;中子散射;胶体;

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1. Micellar structure of a sugar based bolaamphiphile in pure solution and destabilizing effects in mixtures of glycolipids [J] . Garamus VM, Milkereit G, Gerber S, Chemical Physics Letters . 2004,第1a3期

机译：糖基双性亲脂纯溶液的胶束结构和糖脂混合物的去稳定作用
2. Study of the Micellization and Micellar Growth in Pure Alkanediyl-α-ω-Bis(dodecyldimethylammonium) Bromide and MEGA10 Surfactant Solutions and Their Mixtures. Influence of the Spacer on the Enthalpy Change Accompanying Sphere-to-Rod Transitions [J] . Victoria Isabel Martin, Amalia Rodriguez, Maria del Mar Graciani The journal of physical chemistry, B. Condensed matter, materials, surfaces, interfaces & biophysical . 2010,第23期

机译：纯烷烃基-α-ω-双（十二烷基二甲基铵）溴化物和MEGA10表面活性剂溶液及其混合物中胶束化和胶束生长的研究。间隔物对伴随球杆过渡的焓变的影响
3. Formation of High-Axial-Ratio Microstructures from Sugar-, Peptide-, and Nucleobase-based Bolaamphiphiles [J] . Toshimi SHIMIZU 日本油化学会誌 . 2000,第10期

机译：由糖，肽和基于核碱基的Bolaamphiphiles形成高轴向比率的微结构。
4. Brownian Dynamics Simulation of Temperature and Solvent Effects on Micellar Structure and Viscoelastic Behavior of Surfactant Solution [C] . J. J. Wei, Y. Kawaguchi Pacific Rim Conference on Rheology(PRCR4); 20050807-11; Shanghai(CN) . 2005

机译：温度和溶剂对胶束结构和表面活性剂溶液粘弹性行为的布朗动力学模拟
5. Nonlinear oscillatory rheology and structure of wormlike micellar solutions and colloidal suspensions. [D] . Gurnon, Amanda Kate. 2014

机译：蠕虫状胶束溶液和胶体悬浮液的非线性振荡流变学和结构。
6. Nanostructure of Solid Precipitates Obtained by Expansion of Polystyrene-block-Polybutadiene Solutions in Near Critical Propane: Block Ratio and Micellar Solution Effects [O] . Jade Green, Zachary Tyrrell, Maciej Radosz, -1

机译：通过在临界丙烷附近的聚苯乙烯 - 嵌段 - 聚丁二烯溶液中膨胀获得的固体沉淀物的纳米结构：嵌段比和胶束溶液效应
7. Lipoplexes formed from sugar-based gemini surfactants undergo a lamellar-to-micellar phase transition at acidic pH. Evidence for a non-inverted membrane-destabilizing hexagonal phase of lipoplexes [O] . Wasungu Luc, Stuart Marc C. A., Scarzello Marco, 2006

机译：由糖基双子表面活性剂形成的脂质复合物在酸性pH下会经历层状到胶束状的相变。脂质复合物不可逆的破坏膜的六方相的证据

Micellar structure of a sugar based bolaamphiphile in pure solution and destabilizing effects in mixtures of glycolipids

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