A crossed-molecular beam study on collisional ionization dynamics of acetonitrile and benzene molecules with He*(2(3)S) metastable atoms

Horio T.; Maruyama R.; Kishimoto N.; Ohno K.

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A crossed-molecular beam study on collisional ionization dynamics of acetonitrile and benzene molecules with He*(2(3)S) metastable atoms

机译：跨分子束研究He *（2（3）S）亚稳原子与乙腈和苯分子的碰撞电离动力学

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Collision-energy/electron-energy resolved two-dimensional Penning ionization electron spectroscopy has been first applied to crossed molecular beams of CH3CN and C6H6 in interaction with a He*(2(3)S) atom. A comparison of two molecular beam conditions, a seeded supersonic jet and an effusive beam, gave considerable differences in the collision energy dependence of partial ionization cross sections (CEDPICS). Since molecules are randomly oriented in the effusive beam, distorted molecular orientations from the spherical distribution in the supersonic jet are concluded to be responsible for the observed difference in CEDPICS. (C) 2003 Elsevier B.V. All rights reserved. [References: 35]

机译：碰撞能/电子能解析二维潘宁电离电子光谱技术已首先应用于与He *（2（3）S）原子相互作用的CH3CN和C6H6交叉分子束。比较两种分子束条件，即种子超音速射流和喷射射流，在部分电离截面的碰撞能量依赖性（CEDPICS）方面存在很大差异。由于分子在喷流束中随机取向，因此可以推断超音速射流中球形分布中分子取向的畸变是造成CEDPICS中观察到的差异的原因。（C）2003 Elsevier B.V.保留所有权利。 [参考：35]

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《Chemical Physics Letters》 |2004年第3期|共7页
作者
Horio T.; Maruyama R.; Kishimoto N.; Ohno K.;
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正文语种 eng
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Classical trajectory calculations; Der-waals clusters; Penning ionization; Electron-spectroscopy; Energy-dependence; Unsaturated-hydrocarbons; Laser-absorption; Magnetic-field; Kinetic-energy; Orientation;

机译：经典轨迹计算;Der-waals簇;Penning电离;电子光谱;能量依赖;不饱和烃;激光吸收;磁场;运动能;方向;

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1. A crossed-molecular beam study on collisional ionization dynamics of acetonitrile and benzene molecules with He*(2(3)S) metastable atoms [J] . Horio T., Maruyama R., Kishimoto N., Chemical Physics Letters . 2004,第1a3期

机译：跨分子束研究He *（2（3）S）亚稳原子与乙腈和苯分子的碰撞电离动力学
2. Stereodynamics and Outer Valence Ionic States of Ferrocene in Collisional Ionization with a He*(2~3S)Metastable Atom by Two-Dimensional Penning Ionization Electron Spectroscopy [J] . Naoki Kishimoto, Koichi Ohno The journal of physical chemistry, A. Molecules, spectroscopy, kinetics, environment, & general theory . 2009,第3期

机译：二维潘宁电离电子能谱分析He *（2〜3S）亚稳原子碰撞中二茂铁的立体动力学和外价离子态
3. Observation of anisotropic interactions between metastable atoms and target molecules by two-dimensional collisional ionization electron spectroscopy [J] . Kishimoto N, Ohno K International Reviews in Physical Chemistry . 2007,第1期

机译：二维碰撞电离电子光谱法观察亚稳态原子与靶分子之间的各向异性相互作用
4. Cross sections for the collisions of metastable Mg~*(~3P) and Ca~*(~3P, ~1D) atoms with HX molecules (X = F, Cl, Br, I) [C] . B. Pranszke, P. Kierzkowski, A. Kowalski, Atomic and Molecular Physics . 2004

机译：亚稳态Mg〜*（〜3P）和Ca〜*（〜3P，〜1D）原子与HX分子（X = F，Cl，Br，I）碰撞的截面
5. Mass Analyzed Threshold Ionization-Photoion with VUV laser Pulsed Field Ionization and Guided Ion Beam Method Applied to the Study of State-Selected Ion-Molecule Reaction Dynamics. [D] . Xu, Hong. 2011

机译：VUV激光脉冲场电离和引导离子束方法进行质量分析的阈值电离-光电离，用于研究状态选择的离子-分子反应动力学。
6. PNAS Plus: Ab initio dynamics and photoionization mass spectrometry reveal ion–molecule pathways from ionized acetylene clusters to benzene cation [O] . Tamar Stein, Biswajit Bandyopadhyay, Tyler P. Troy, 2017

机译：PNAS Plus：从头算动力学和光电离质谱揭示了从离子化乙炔簇到苯阳离子的离子-分子途径
7. Application of Quantum Mechanics to Fundamental Interactions in Chemical Physics: Studies of Atom-Molecule and Ion-Molecule Interactions Under Single-Collision Conditions: Crossed Molecular Beams; Single-Crystal Mössbauer Spectroscopy: Microscopic Tensor Properties of ⁵⁷Fe Sites in Inorganic Ferrous High-Spin Compounds [O] . Bull James 2010

机译：量子力学在化学物理学中基本相互作用中的应用：单碰撞条件下原子-分子和离子-分子相互作用的研究：交叉分子束单晶体Mössbauer光谱：无机亚铁高旋转化合物中CompoundFe位的微观张量性质
8. The Decay of Optically Thick Helium Plasmas, Taking into Account Ionizing Collisions between Metastable Atoms or Molecules [R] . J. Stevefelt 1970

机译：光学厚氦等离子体的衰变，考虑到亚稳态原子或分子之间的电离碰撞

A crossed-molecular beam study on collisional ionization dynamics of acetonitrile and benzene molecules with He*(2(3)S) metastable atoms

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