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首页> 外文期刊>Chemical Physics Letters >Observation of intramolecular defects in n-alkanes C25H52-C29H60 by the positron annihilation method
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Observation of intramolecular defects in n-alkanes C25H52-C29H60 by the positron annihilation method

机译:正电子an没法观察正构烷烃C25H52-C29H60的分子内缺陷

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摘要

The lifetime of ortho-positronium (o-Ps) in solid phases of long-chain n-alkanes was measured. In even-numbered alkanes, only one phase transition is observed; a very long lifetime is related to large free volumes near kink-shaped conformers. In odd-numbered alkanes (n less than or equal to 25), another solid phase (phase IV) is characterized by slightly increased o-Ps lifetime, which means the domination of end-gauche and double-gauche intramolecular defects. In C29H60 the structure of defects changes continuously in the whole range of phase IV. (C) 2004 Elsevier B.V. All rights reserved.
机译:测量了长链正构烷烃固相中邻位正电子(o-Ps)的寿命。在偶数烷烃中,仅观察到一个相变。非常长的使用寿命与扭结形适形器附近的大量自由体积有关。在奇数烷烃(n小于或等于25)中,另一种固相(相IV)的特征是o-Ps寿命略有延长,这意味着端胶和双胶分子内缺陷占主导地位。在C29H60中,缺陷的结构在IV相的整个范围内连续变化。 (C)2004 Elsevier B.V.保留所有权利。

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