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首页> 外文期刊>Chemical Physics Letters >Femtosecond pump-broadband probe study of primary doped polyaniline - The evidence of neutral primary photoexcitations
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Femtosecond pump-broadband probe study of primary doped polyaniline - The evidence of neutral primary photoexcitations

机译:飞秒泵浦宽带探测初级掺杂聚苯胺的研究-中性初级光激发的证据

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摘要

A film and a water solution of primary doped polyaniline were studied by means of femtosecond pump-probe spectroscopy in the 425-1050 nm spectral interval. Data at wavelengths from 425 to 650 nm were recorded for the first time. Primary photoexcitations created by pulses at 800 and 400 nm are treated as charge-transfer excitons in amorphous films and in globular aggregates of the solution. Ultrafast dynamics are interpreted as similar to 1 ps exciton dissociation and formation of separate charge carriers. It was found that charged species cause specific spectral deformation and have a lifetime of about 7 ps.
机译:通过飞秒泵浦探针光谱法在425-1050 nm的光谱区间内研究了一次掺杂的聚苯胺的薄膜和水溶液。第一次记录了从425到650 nm波长的数据。由800和400 nm脉冲产生的主要光激发被视为非晶膜和溶液的球状聚集体中的电荷转移激子。超快动力学被解释为类似于1 ps激子解离和单独电荷载流子的形成。发现带电物质引起特定的光谱变形,并且具有约7ps的寿命。

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