Impact of choice of alkane deposition solvent on 4-fluorobenzoic acid layers adsorbed on silver nanostructures

Cordova S.; Schiefer E.; Bonde A.; Razer T.; Chen T.; Perry D.

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Impact of choice of alkane deposition solvent on 4-fluorobenzoic acid layers adsorbed on silver nanostructures

机译：烷烃沉积溶剂的选择对银纳米结构上吸附的4-氟苯甲酸层的影响

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Surface-enhanced infrared absorption (SEIRA) experiments revealed that the chain length and evaporation rate of alkane deposition solvents altered 4-fluorobenzoic acid (4FBA) adsorption. 4FBA did not dissociate in the multilayer with the fast-evaporating n-pentane deposition solvent. However, with n-hexane and heavier solvents, the evaporation rate was slow enough to allow significant formation of 4-fluorobenzoate ions (4FBI) in the multilayer. Strong intermolecular attractions were present with heavier deposition solvents as evidenced by the incorporation of n-heptane into the 4FBI multilayer. This work will apply to many synthetic, biological, and environmental areas involving the interaction of metal nanostructures with oxygenated or halogenated hydrocarbons.

机译：表面增强红外吸收（SEIRA）实验表明，烷烃沉积溶剂的链长和蒸发速率改变了4-氟苯甲酸（4FBA）的吸附。 4FBA不会与快速蒸发的正戊烷沉积溶剂在多层中解离。但是，使用正己烷和较重的溶剂时，蒸发速度足够慢，以至于无法在多层结构中显着形成4-氟苯甲酸酯离子（4FBI）。正庚烷结合到4FBI多层膜中可以证明，较重的沉积溶剂具有很强的分子间吸引力。这项工作将适用于涉及金属纳米结构与氧化或卤代烃相互作用的许多合成，生物学和环境领域。

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《Chemical Physics Letters》 |2010年第3期|共5页
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Cordova S.; Schiefer E.; Bonde A.; Razer T.; Chen T.; Perry D.;
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1. Impact of choice of alkane deposition solvent on 4-fluorobenzoic acid layers adsorbed on silver nanostructures [J] . Cordova S., Schiefer E., Bonde A., Chemical Physics Letters . 2010,第1a3期

机译：烷烃沉积溶剂的选择对银纳米结构上吸附的4-氟苯甲酸层的影响
2. Silver particles-modified polysulfonic acid-doped polyaniline layers: Electroless deposition of silver in slightly acidic and neutral solutions [J] . Lyutov V., Tsakova V. Journal of solid state electrochemistry . 2011,第11a12期

机译：银粒子改性的聚磺酸掺杂的聚苯胺层：在弱酸性和中性溶液中化学沉积银
3. Surface-Enhanced Vibrational Spectroscopy and Density Functional Theory Study of Isoniazid Layers Adsorbed on Silver Nanostructures [J] . Owen Aaron R., Golden Jon W., Price Adam S., The journal of physical chemistry, C. Nanomaterials and interfaces . 2014,第50期

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机译：银片基质上吸附的硬脂酸吸附层的振动分析
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机译：吸附在胶体银上的半抗原（2，4-二硝基苯基氨基酸）的表面拉曼散射和透射电镜。
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机译：银岛薄膜上磺胺丁胺吸附的Langmuir-Blodgett层：探针距离对金属增强荧光的影响
7. Solvent Effects on the Monolayer Structure of Long n-Alkane Molecules Adsorbed on Graphite [O] . Herwig, K. W., Matthies, Blake E. (Blake Edward), 1968-, Taub, Haskell 1995

机译：溶剂对石墨上吸附的长正构烷烃分子单层结构的影响
8. Structure and Composition of Adsorbed Layers Formed by Sequential Exposure of Pt(100) and Pt(111) to Pairs of Compounds: Solvents and Electrolytic Substances [R] . Katekaru, J. Y., Garwood, G. A., Hershberger, J. F., 1982

机译：pt（100）和pt（111）顺序暴露于化合物对形成的吸附层的结构和组成：溶剂和电解物质

Impact of choice of alkane deposition solvent on 4-fluorobenzoic acid layers adsorbed on silver nanostructures

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