OH initiated oxidation of 1,3-butadiene in the presence of O_2 and NO

Ghosh B.; Park J.; Anderson K.C.; North S.W.

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OH initiated oxidation of 1,3-butadiene in the presence of O_2 and NO

机译：在O_2和NO存在下OH引发1,3-丁二烯的氧化

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The OH radical initiated oxidation of 1,3-butadiene was studied under high NOx conditions by the LP-LIF method. We report a rate constant of (7.0 ± 0.3) × 10~(-11) s~(-1) molecule~(-1) cm ~3 for OH addition to 1,3-butadiene which agrees well with values reported previously. Based on the analysis of OH cycling data combined with results of earlier isomeric selective studies, we have determined a branching ratio for the major hydroxy alkyl channel to be 0.87 ± 0.08. Using this branching ratio, we have predicted the end product distribution for OH radical initiated oxidation of 1,3-butadiene and provide a condensed chemical mechanism. This study synthesizes previous work on OH initiated1,3-butadiene oxidation under high NOx conditions.

机译：通过LP-LIF方法研究了在高NOx条件下OH自由基引发的1,3-丁二烯的氧化。我们报道了在1,3-丁二烯中添加OH的速率常数为（7.0±0.3）×10〜（-11）s〜（-1）分子〜（-1）cm〜3，这与先前报道的值非常吻合。基于对OH循环数据的分析以及较早的异构体选择性研究的结果，我们确定了主要羟烷基通道的支化比为0.87±0.08。使用该支化比，我们已经预测了OH自由基引发的1,3-丁二烯氧化的最终产物分布，并提供了一个浓缩的化学机理。这项研究综合了以前在高NOx条件下OH引发的1,3-丁二烯氧化的工作。

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《Chemical Physics Letters》 |2010年第3期|共6页
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Ghosh B.; Park J.; Anderson K.C.; North S.W.;
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1. OH initiated oxidation of 1,3-butadiene in the presence of O_2 and NO [J] . Ghosh B., Park J., Anderson K.C., Chemical Physics Letters . 2010,第1a3期

机译：在O_2和NO存在下OH引发1,3-丁二烯的氧化
2. Microstructure-Thermal Property Relationship of High trans-1,4-Poly(butadiene) Produced by Anionic Polymerization of 1,3-Butadiene Using an Initiator Composed of Alkyl Aluminum, n-Butyl Lithium, and Barium Alkoxide [J] . Juan J Benvenuta-Tapia José A Tenorio-López Rafael Herrera-Nájera Leonardo Ríos-Guerrero Polymer Engineering and Science . 2009,第1期

机译：使用烷基铝，正丁基锂和烷氧基钡组成的引发剂，通过1,3-丁二烯的阴离子聚合反应生成的高反式1,4-聚丁二烯的微观结构-热性质关系
3. Microstructure-Thermal Property Relationship of High trans-1,4-Poly(butadiene)Produced by Anionic Polymerization of 1,3-Butadiene Using an Initiator Composed of Alkyl Aluminum,n-Butyl Lithium,and Barium Alkoxide [J] . Juan J.Benvenuta-Tapia, Jose A.Tenorio-Lopez, Rafael Herrera-Najera Polymer engineering and science . 2009,第1期

机译：由烷基铝，正丁基锂和烷氧基钡组成的引发剂阴离子聚合1,3-丁二烯制备的高反式1,4-聚（丁二烯）的微观结构-热性质关系
4. Secondary vinylic radicals in 1,3-butadiene systems and their reactions with O_2: A theoretical study of thermochemical properties, reaction paths, and kinetics [C] . Leo Rutz, Gabriel da Silva, Joseph W. Bozzelli, US Combustion Meeting; 20070325-28; San Diego,CA(US) . 2007

机译：1,3-丁二烯体系中的次级乙烯基自由基及其与O_2的反应：热化学性质，反应路径和动力学的理论研究
5. Anionic synthesis of well-defined, three-armed, star-branched, tapered block copolymers of styrene and 1,3-butadiene by using a trifunctional organolithium initiator. [D] . Moctezuma Espiricueto, Sergio Alberto. 2003

机译：通过使用三官能有机锂引发剂阴离子合成苯乙烯，1,3-丁二烯的定义明确的三臂星形分支的锥形嵌段共聚物。
6. Formation of phenylacetic acid and benzaldehyde by degradation of phenylalanine in the presence of lipid hydroperoxides: New routes in the amino acid degradation pathways initiated by lipid oxidation products [O] . Francisco J. Hidalgo, Rosario Zamora 2019

机译：在脂质氢过氧化物的存在下通过苯丙氨酸的降解形成苯乙酸和苯甲醛：由脂质氧化产物引发的氨基酸降解途径的新途径
7. The OH-Initiated Oxidation of 1,3-Butadiene in the Presence of O2 and NO: A Photolytic Route To Study Isomeric Selective Reactivity [O] . Stephen A. Miller, Renyi Zhang, Simon W. North 2015

机译：在O2和NO存在下OH-引发的1,3-丁二烯氧化：研究异构选择反应性的光解途径
8. Epoxidation of E-1,4-poly(2-triethylsilyl-1,3-butadiene) and E-1,4-poly-(2,3-bis(trimethylsilyl)-1,3-butadiene). Stereochemical analysis of E-1,4-poly(2,3-epoxy-2-triethylsilyl-1,3-butadiene) and E-1,4-poly-(2,3-bis(trimethylsilyl [R] . Jiang, W., Weber, W. P. 1988

机译：E-1,4-聚（2-三乙基甲硅烷基-1,3-丁二烯）和E-1,4-聚 - （2,3-双（三甲基甲硅烷基）-1,3-丁二烯）的环氧化。 E-1,4-聚（2,3-环氧-2-甲基甲硅烷基-1,3-丁二烯）和E-1,4-聚 - （2,3-双（三甲基甲硅烷基）的立体化学分析

OH initiated oxidation of 1,3-butadiene in the presence of O_2 and NO

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