Novel Organic-Inorganic Hybrid Electrolyte to Enable LiFePO4 Quasi-Solid-State Li-Ion Batteries Performed Highly around Room Temperature

Tan Rui; Gao Rongtan; Zhao Yan; Zhang Mingjian; Xu Junyi; Yang Jinlong; Pan Feng

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Novel Organic-Inorganic Hybrid Electrolyte to Enable LiFePO4 Quasi-Solid-State Li-Ion Batteries Performed Highly around Room Temperature

机译：新型LiaPO4准固态锂离子电池的有机-无机混合电解质，在室温下具有很高的性能

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A novel type of organic-inorganic hybrid polymer electrolytes with high electrochemical performances around room temperature is formed by hybrid of nanofillers, Y-type oligomer, polyoxyethylene and Li-salt (PBA-Li), of which the T-g and T-m are significantly lowered by blended heterogeneous polyethers and embedded nanofillers with benefit of the dipole modification to achieve the high Li-ion migration due to more free-volume space. The quasi-solid-state Li-ion batteries based on the LiFePO4/15PBA-Li/Li-metal cells present remarkable reversible capacities (133 and 165 mAh g(-1) @0.2 C at 30 and 45 degrees C, respectively), good rate ability and stable cycle performance (141.9 mAh g(-1) @0.2 C at 30 degrees C after 150 cycles).

机译：通过纳米填料，Y型低聚物，聚氧乙烯和锂盐（PBA-Li）的混合形成了一种新型的有机-无机杂化聚合物电解质，该电解质在室温附近具有很高的电化学性能，其Tg和Tm显着降低了。混合的异质聚醚和嵌入式纳米填料，具有偶极子修饰的优点，由于有更多的自由空间，因此可以实现高锂离子迁移。基于LiFePO4 / 15PBA-Li / Li-金属电池的准固态锂离子电池具有显着的可逆容量（分别在30和45摄氏度时在0.2 C时为133和165 mAh g（-1）），良好的速率能力和稳定的循环性能（150个循环后，在30摄氏度下于0.2 C时141.9 mAh g（-1））。

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《ACS applied materials & interfaces》 |2016年第45期|共8页
作者
Tan Rui; Gao Rongtan; Zhao Yan; Zhang Mingjian; Xu Junyi; Yang Jinlong; Pan Feng;
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polymers; hybrid electrolyte membranes; quasi-solid-state lithium ion batteries; stable performances; room temperature;

机译：聚合物;混合电解质膜;准固态锂离子电池;性能稳定;室温;

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1. Novel Organic-Inorganic Hybrid Electrolyte to Enable LiFePO4 Quasi-Solid-State Li-Ion Batteries Performed Highly around Room Temperature [J] . Tan Rui, Gao Rongtan, Zhao Yan, ACS applied materials & interfaces . 2016,第45期

机译：新型LiaPO4准固态锂离子电池的有机-无机混合电解质，在室温下具有很高的性能
2. Flexible quasi-solid-state zinc ion batteries enabled by highly conductive carrageenan bio-polymer electrolyte [J] . Yuan Huang, Jiuwei Liu, Jiyan Zhang, RSC Advances . 2019,第29期

机译：高导电角叉菜胶生物聚合物电解质可实现准固态锌离子柔性电池
3. Fabrication of in operando, self-growing, core-shell solid electrolyte interphase on LiFePO4 electrodes for preventing undesirable high-temperature effects in Li-ion batteries [J] . Wang Fu-Ming, Kuo Yu-Lin, Huang Li-Shan, Electrochimica Acta . 2018,第期

机译：在操作组织的制造，自我生长，核心 - 壳固体电解质对LiFepo4电极的相互作用，用于防止锂离子电池中的不希望的高温效应
4. TOBACCO MOSAIC VIRUS ENABLED SI ANODES AND LIFEPO4 CATHODES FOR LI-ION BATTERIES [C] . Chunsheng Wang, Xilin Chen, Yihang Liu American Chemical Society National Meeting . 2012

机译：烟草马赛克病毒使SI阳极和Lifepo4阴极用于锂离子电池
5. Highly Branched Crosslinked Poly(ethylene oxide) for Li-ion Battery Electrolytes. [D] . Paranjape, Nachiket. 2016

机译：用于锂离子电池电解质的高度支化的交联聚环氧乙烷。
6. Data on effect of electrospinning conditions on morphology and effect of heat-treatment temperature on the cycle and rate properties of core-shell LiFePO4/FeS/C composite fibers for use as cathodes in Li-ion batteries [O] . Rattiya Hongtong, Panya Thanwisai, Rattakarn Yensano, 2019

机译：静电纺丝条件对形貌的影响以及热处理温度对用作锂离子电池正极的核壳型LiFePO4 / FeS / C复合纤维的循环和速率特性的影响的数据
7. Novel OrganicInorganic Hybrid Electrolyte to Enable LiFePO4 Quasi-Solid-State Li-Ion Batteries Performed Highly around Room Temperature [O] . -1

机译：新型有机型杂化电解质，使Lifepo4准固态锂离子电池高度约束室温
8. DOE-Final Report, Multi-Hybrid Power Vehicles with Cost-Effective and Durable Polymer Electrolyte Membrane Fuel Cell and Li-Ion Battery [R] . Bose, A 2014

机译：DOE-最终报告，具有成本效益和耐用的聚合物电解质膜燃料电池和锂离子电池的多混合动力汽车

Novel Organic-Inorganic Hybrid Electrolyte to Enable LiFePO4 Quasi-Solid-State Li-Ion Batteries Performed Highly around Room Temperature

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