...
  • 主题
高级搜索  >
历史搜索 清空历史
首页> 外文期刊>Angewandte Chemie >Double Siegle-Crystal-to-Single-Crystal Transformation and Small-Molecule Activation In Rhodium NHC Complexes
【24h】

Double Siegle-Crystal-to-Single-Crystal Transformation and Small-Molecule Activation In Rhodium NHC Complexes

机译：铑NHC络合物中的双Siegle-Crystal到Single-Crystal转化和小分子活化

获取原文
获取原文并翻译 | 示例
           
页面导航
  • 摘要
  • 著录项
  • 相似文献
  • 相关主题

摘要

Examples of chemical reactions that occur in the solid state without disruption of crystalline order are quite rare. The most prevalent among these are photochemical reactions, absorption/desorption of solvents from porous materials, or changes in coordination polymers. There are very few examples of single-crystal-to-single-crystal reactions of mono-molecular species being reported and even fewer examples of such transformations of organometallic compounds. Notable exceptions include the recent elegant reports by van Koten, Brookhart, and McKeown, which describe single-crystal-to-single-crystal transformations in which the coordination environment around a transition metal changes. These transformations are of significant interest in terms of crystal engineering, chemical sensing, and materials science in general.
机译：固态发生而没有破坏结晶顺序的化学反应的例子是非常罕见的。其中最普遍的是光化学反应，多孔材料中溶剂的吸收/解吸或配位聚合物的变化。报道的单分子种类的单晶至单晶反应的例子很少，而有机金属化合物的这种转化的例子更少。著名的例外包括van Koten，Brookhart和McKeown最近发表的精美报告，它们描述了单晶到单晶的转变，其中过渡金属周围的配位环境发生了变化。一般而言，这些转换在晶体工程，化学传感和材料科学方面具有重大意义。

著录项

相似文献

  • 外文文献
  • 中文文献
  • 专利
获取原文

客服邮箱：kefu@zhangqiaokeyan.com

京公网安备：11010802029741号 ICP备案号：京ICP备15016152号-6 六维联合信息科技 (北京) 有限公司©版权所有

  • 客服微信

  • 服务号