On the Interpretation of Deuterium Kinetic Isotope Effects in C-H Bond Functionalizations by Transition-Metal Complexes

Eric M. Simmons; John F. Hartwig

首页> 外文期刊>Angewandte Chemie >On the Interpretation of Deuterium Kinetic Isotope Effects in C-H Bond Functionalizations by Transition-Metal Complexes

【24h】

On the Interpretation of Deuterium Kinetic Isotope Effects in C-H Bond Functionalizations by Transition-Metal Complexes

机译：用过渡金属配合物解释C-H键功能化中的氘代动力学同位素效应

获取原文

获取原文并翻译 | 示例

掌桥外文数据库（机构版） >>

开具论文收录证明 >>

文献代查 >>

页面导航

摘要
著录项
相似文献
相关主题

摘要

A detailed understanding of the mechanism by which a chemical reaction proceeds enables one to control and improve a given synthetic process. Only by understanding the factors that govern the rate and selectivity of a transformation can the outcome of the reaction be precisely modulated through design of the catalyst, reagents, and conditions. Historically, the field of physical organic chemistry was born from the desire to understand the intimate details of the reactions of organic molecules, and the principles that have emerged from this work have been vital to the development of synthetic organic chemistry.

机译：对化学反应进行机理的详细理解使人们能够控制和改进给定的合成过程。只有了解了控制转化速率和选择性的因素，才能通过催化剂，试剂和条件的设计来精确调节反应的结果。从历史上看，物理有机化学领域源于对有机分子反应的内在细节的了解，而这项工作中产生的原理对于合成有机化学的发展至关重要。

著录项

来源
《Angewandte Chemie》 |2012年第13期|共7页
作者
Eric M. Simmons; John F. Hartwig;
展开▼
作者单位

展开▼
收录信息
原文格式 PDF
正文语种 eng
中图分类
关键词
C-H functionalization; energy diagrams; isotope effects; kinetics; rate-determining step;

机译：碳氢官能化;能图;同位素效应;动力学;速率确定步骤;

相似文献

外文文献
中文文献
专利

1. On the Interpretation of Deuterium Kinetic Isotope Effects in C-H Bond Functionalizations by Transition-Metal Complexes [J] . Eric M. Simmons, John F. Hartwig Angewandte Chemie . 2012,第13期

机译：用过渡金属配合物解释C-H键功能化中的氘代动力学同位素效应
2. Functionalization of the C-H Bond of N-Heteroaromatics Assisted by Early Transition-Metal Complexes [J] . Nagae Haruki, Kundu Abhinanda, Inoue Mariko, Asian Journal of Organic Chemistry . 2018,第7期

机译：早期过渡 - 金属配合物辅助N-杂芳烃C-H键的官能化
3. Theoretical study on kinetic isotope effects in the C-H bond activation of alkanes by iron-oxo complexes [J] . Kazunari Yoshizawa Coordination chemistry reviews . 2002,第1a2期

机译：铁-氧配合物活化烷烃的C-H键动力学同位素效应的理论研究
4. Kinetic and Equilibrium Deuterium Isotope Effects for C-H Bond Reductive Elimination and Oxidative Addition Reactions Involving the Ansa-Tungstenocene Methyl-Hydride Complex Me_2Si(C_5Me_4)_2W(Me)H [C] . Kevin E. Janak, David G. Churchill, Gerard parkin American Chemical Society National Meeting . 2004

机译：动力学和均衡氘同位素对C-H键的减少消除和氧化添加反应涉及Ansa-钨烯甲基 - 氢化物复合物ME_2SI（C_5ME_4）_2 W（ME）H.
5. Catalytic C-H Bond Functionalization by Nickel(0) N-Heterocyclic Carbene Complexes: Influence of Ligand Sterics on Selective Silylation [D] . Elsby, Matthew Ryan. 2017

机译：镍（0）N-杂环碳烯络合物的催化C-H键官能化：配体的立体异构体对选择性硅烷化的影响
6. Two-State Reactivity Model Explains Unusual Kinetic Isotope Effect Patterns in C-H Bond Cleavage by Nonheme Oxoiron(IV) Complexes [O] . Dr. Eric J. Klinker, Dr. Sason Shaik, Dr. Hajime Hirao, -1

机译：两种反应模型解释了非血红素氧合铁（IV）配合物在C-H键裂解中的异常动力学同位素效应模式
7. Kinetics and Mechanism of N2 Hydrogenation in Bis(cyclopentadienyl) Zirconium Complexes and Dinitrogen Functionalization by 1, 2-Addition of a Saturated C-H Bond [O] . -1

机译：双（环戊二烯基）锆配合物中N2氢化的动力学和机理1，2-加入饱和C-H键

相关主题

On the Interpretation of Deuterium Kinetic Isotope Effects in C-H Bond Functionalizations by Transition-Metal Complexes

摘要

著录项

相似文献

相关主题

期刊订阅