One-Pot Synthesis of Isoquinolinium Salts by Rhodium-Catalyzed C-H Bond Activation: Application to the Total Synthesis of Oxychelerythrine

Jayachandran Jayakumar; Kanniyappan Parthasarathy; Chien-Hong Cheng

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One-Pot Synthesis of Isoquinolinium Salts by Rhodium-Catalyzed C-H Bond Activation: Application to the Total Synthesis of Oxychelerythrine

机译：铑催化的C-H键活化一锅法合成异喹啉鎓盐：在氧化白屈菜红碱的全合成中的应用

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Highly substituted isoquinolinium salts are valuable and versatile intermediates for synthetic organic chemistry and are widely utilized for the construction of various natural products and bioactive molecules. The traditional methods for the synthesis of isoquinolinium salts from isoquinolines and alkyl halide derivatives is limited by the number of substituted isoquinolines that are readily available.

机译：高度取代的异喹啉鎓盐是合成有机化学的宝贵且用途广泛的中间体，被广泛用于构建各种天然产物和生物活性分子。由异喹啉和烷基卤化物衍生物合成异喹啉鎓盐的传统方法受到容易获得的取代异喹啉的数量的限制。

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《Angewandte Chemie》 |2012年第1期|共4页
作者
Jayachandran Jayakumar; Kanniyappan Parthasarathy; Chien-Hong Cheng;
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原文格式 PDF
正文语种 eng
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关键词
alkynes; annulation; C-H activation; heterocycles; rhodium;

机译：炔烃;环化;C-H活化;杂环;铑;

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1. One-Pot Synthesis of Isoquinolinium Salts by Rhodium-Catalyzed C-H Bond Activation: Application to the Total Synthesis of Oxychelerythrine [J] . Jayachandran Jayakumar, Kanniyappan Parthasarathy, Chien-Hong Cheng Angewandte Chemie . 2012,第1期

机译：铑催化的C-H键活化一锅法合成异喹啉鎓盐：在氧化白屈菜红碱的全合成中的应用
2. Rh(Ⅲ)-catalyzed synthesis of 1-substituted isoquinolinium salts via a C-H bond activation reaction of ketimines with alkynes [J] . Natarajan Senthilkumar, Parthasarathy Gandeepan, Jayachandran Jayakumar, Chemical Communications . 2014,第23期

机译：Rh（Ⅲ）通过酮亚胺与炔烃的C-H键活化反应催化合成1-取代的异喹啉鎓盐
3. Ru(II)-catalyzed C-H bond activation for the synthesis of substituted isoquinolinium salts from benzaldehydes, amines, and alkynes [J] . Parthasarathy K., Senthilkumar N., Jayakumar J., Organic letters . 2012,第13期

机译：Ru（II）催化的C-H键活化，用于从苯甲醛，胺和炔烃合成取代的异喹啉鎓盐
4. Unprecedented Synthesis of 1,3-dialkylimidazolium- 2-carboxylate: Applications in the Synthesis of Halogen-Free Ionic Liquids and Reactivity as Carbon Dioxide Transfer Agent to Active C-H Bonds [C] . M. Aresta, I. Tkatchenko, I. Tommasi, Symposium ionic liquids as green solvents: Progress and prospects . 2003

机译：前所未有的合成1,3-二烷基咪唑鎓-2-羧酸盐：在合成无卤离子液体和反应性中作为二氧化碳转移剂的应用，以活性C-H键合
5. Synthesis and Characterization of Group VIII & IX Transition Metal Complexes and Their Application in C-H Bond Activation and Hydrogen Transformation [D] . Yuan, Hongmei. 2018

机译：VIII和IX过渡金属配合物组的合成与表征及其在C-H键活化和氢转化中的应用
6. Reactivity of 3-Ethoxycarbonyl Isoquinolinium Salts Towards Various Nucleophilic Reagents: Applications to the Synthesis of New 12-Dihydroisoquinoline-3-carboxylates [O] . Mohamed Ameziane Aït Amer Meziane, Jean Pierre Bazureau 2002

机译：3-乙氧基羰基异喹啉鎓盐对各种亲核试剂的反应性：在合成新的12-二氢异喹啉-3-羧酸酯中的应用
7. Rhodium-catalyzed C-H bond activation for the synthesis of quinonoid compounds: Significant Anti-Trypanosoma cruzi activities and electrochemical studies of functionalized quinones [O] . Jardim, Guilherme A.M., Silva, Thaissa L., Goulart, Marilia O.F., 2018

机译：铑催化的C-H键活化，用于合成醌类化合物：显着的抗克鲁氏锥虫活性和功能化醌的电化学研究

One-Pot Synthesis of Isoquinolinium Salts by Rhodium-Catalyzed C-H Bond Activation: Application to the Total Synthesis of Oxychelerythrine

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