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Size dependence of harvested BaTiO_3 nanoparticles on the electro-optic and dielectric properties of ferroelectric liquid crystal nanocolloids

机译:BaTiO_3纳米粒子的尺寸依赖性对铁电液晶纳米胶体的电光和介电性能的影响

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摘要

The influence of the size of harvested barium titanate nanoparticles on the properties of ferroelectric liquid crystal (FLC) nanocolloids was investigated by electro-optical and dielectric methods. The spontaneous polarization and the switching time are decreased for the liquid crystalline nanocolloids compared to nondoped FLC mixtures of different dipole strengths; this dependence is stronger for small size particles (9 nm) and weaker for larger size particles (26 nm) by the same concentration in weight. The decrease of the Goldstone mode (GM) relaxation frequency and the decrease of the dielectric GM absorption strength of the nanocomposites compared to the nondoped FLC mixture go stepwise with the increase of the nanoparticles diameter. Results have been interpreted via strong interaction between the FLC dipoles and the dipoles of the highly polar barium titanate nanoparticles.
机译:通过电光和介电方法研究了收获的钛酸钡纳米粒子的尺寸对铁电液晶纳米胶体性能的影响。与不同偶极强度的非掺杂FLC混合物相比,液晶纳米胶体的自发极化和转换时间减少。在相同的重量浓度下,这种依赖性对于小尺寸颗粒(9 nm)更强,而对大尺寸颗粒(26 nm)更弱。与未掺杂的FLC混合物相比,纳米复合材料的Goldstone模(GM)弛豫频率的降低和介电GM吸收强度的降低随着纳米颗粒直径的增加而逐步增加。通过FLC偶极子与高极性钛酸钡纳米粒子的偶极子之间的强相互作用来解释结果。

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