1'Bi~(2+)/M~(2+)Oxyphosphate:A Continuous Series of Polycationic Species from the 1D Single Chain to the 2D Planes.Part 2:Crystal Structure of Three Original Structural Types Showing a Combination of New Ribbonlike Polycations

Marie Colmont; Marielle Huve; Olivier Mentre

首页> 外文期刊>Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics >1'Bi~(2+)/M~(2+)Oxyphosphate:A Continuous Series of Polycationic Species from the 1D Single Chain to the 2D Planes.Part 2:Crystal Structure of Three Original Structural Types Showing a Combination of New Ribbonlike Polycations

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1'Bi~(2+)/M~(2+)Oxyphosphate:A Continuous Series of Polycationic Species from the 1D Single Chain to the 2D Planes.Part 2:Crystal Structure of Three Original Structural Types Showing a Combination of New Ribbonlike Polycations

机译：1'Bi〜（2 +）/ M〜（2+）氧代磷酸盐：从一维单链到二维平面的一系列连续的聚阳离子物种。第二部分：三种原始结构类型的晶体结构，显示出新型带状聚阳离子的组合

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With the assistance of structural models deduced from the high-resolution electron microscope(HREM)investigation presented in Part 1 of this work,three new structural types were pointed out in Bi_2O_3-MO-P_2O_5 ternary systems.Their crystal structures are built on the arrangement of 2D polycationic ribbons formed of edge-sharing O(Bi,M)_4 tetrahedra and isolated by PO_4 groups.Prior to this study,materials with ribbons up to n = 3 tetrahedra wide have been discovered.The original structures presented here display longer n = 4-6 cases,which suggests a possible continuous series of polycationic entities that range from the single chain(one tetrahedron wide)to the infinite[Bi_2O_2]~(2+)Aurivillius layer.The ribbons with n > 3 show strong structural modifications that are able to bring a good ribbon-phosphate cohesion.In addition to these fascinating structural results,this work fully confirms the validity of the decoding established from HREM images of a single crystallite in inhomogeneous mixtures.

机译：借助本文第1部分中提出的高分辨率电子显微镜（HREM）研究推导的结构模型，在Bi_2O_3-MO-P_2O_5三元体系中指出了三种新的结构类型。由O_（Bi，M）_4边共享O_（Bi，M）_4四面体形成并被PO_4组隔离的2D聚阳离子带。在此研究之前，已经发现了带宽度最大为n = 3四面体的材料。此处显示的原始结构显示更长的n = 4-6例，这表明可能存在一系列连续的聚阳离子实体，范围从单链（一个四面体宽）到无限的[Bi_2O_2]〜（2+）耳孔层。n> 3的带显示出强烈的结构修饰除了这些引人入胜的结构结果外，这项工作还充分证实了由非均质单晶的HREM图像建立的解码的有效性。的混合物。

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《Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics》 |2006年第17期|共10页
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Marie Colmont; Marielle Huve; Olivier Mentre;
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1. 1'Bi~(2+)/M~(2+)Oxyphosphate:A Continuous Series of Polycationic Species from the 1D Single Chain to the 2D Planes.Part 2:Crystal Structure of Three Original Structural Types Showing a Combination of New Ribbonlike Polycations [J] . Marie Colmont, Marielle Huve, Olivier Mentre Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2006,第17期

机译：1'Bi〜（2 +）/ M〜（2+）氧代磷酸盐：从一维单链到二维平面的一系列连续的聚阳离子物种。第二部分：三种原始结构类型的晶体结构，显示出新型带状聚阳离子的组合
2. Bi3+/M2+ oxyphosphate: A continuous series of polycationic species from the 1D single chain to the 2D planes. Part 2: Crystal structure of three original structural types showing a combination of new ribbonlike polycations [J] . Colmont M, Huve M, Mentre O Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2006,第17期

机译：Bi3 + / M2 +氧磷酸盐：从一维单链到二维平面的一系列连续的聚阳离子物质。第2部分：三种原始结构类型的晶体结构，显示了新的带状聚阳离子的组合
3. Bi3+/M2+ oxyphosphate: A continuous series of polycationic species from the 1D single chain to the 2D planes. Part 1: From HREM images to crystal-structure deduction [J] . Huve M, Colmont M, Mentre O Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2006,第17期

机译：Bi3 + / M2 +氧磷酸盐：从一维单链到二维平面的一系列连续的聚阳离子物质。第1部分：从HREM图像到晶体结构推导
4. Design of New Structural Types from Oxocentered Tetrahedra: Continuous Polycationic Series from 1D Chains to 2D Planes in New Bismuth Compounds [C] . Olivier Mentre, Marie Colmont, Marielle Huve Materials Research Society Symposium on Solid-State Chemistry of Inorganic Materials . 2006

机译：来自obocentered tetrahedra的新结构类型的设计：从1d链到新的铋化合物的连续聚阳离子系列到2D平面
5. Bi3+/M2+ Oxyphosphate: A Continuous Series of Polycationic Species from the 1D Single Chain to the 2D Planes. Part 2: Crystal Structure of Three Original Structural Types Showing a Combination of New Ribbonlike Polycations [O] . -1

机译：Bi3 + / M2 +梭磷酸：从1D单链到2D平面的连续系列的聚阳离子物种。第2部分：三个原始结构类型的晶体结构，显示新的丝带般的泛杂化的组合

1'Bi~(2+)/M~(2+)Oxyphosphate:A Continuous Series of Polycationic Species from the 1D Single Chain to the 2D Planes.Part 2:Crystal Structure of Three Original Structural Types Showing a Combination of New Ribbonlike Polycations

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